Theoretical advances in polariton chemistry and molecular cavity quantum electrodynamics

A Mandal, MAD Taylor, BM Weight… - Chemical …, 2023 - ACS Publications
When molecules are coupled to an optical cavity, new light–matter hybrid states, so-called
polaritons, are formed due to quantum light–matter interactions. With the experimental …

The rise and current status of polaritonic photochemistry and photophysics

R Bhuyan, J Mony, O Kotov, GW Castellanos… - Chemical …, 2023 - ACS Publications
The interaction between molecular electronic transitions and electromagnetic fields can be
enlarged to the point where distinct hybrid light–matter states, polaritons, emerge. The …

Manipulating matter by strong coupling to vacuum fields

FJ Garcia-Vidal, C Ciuti, TW Ebbesen - Science, 2021 - science.org
BACKGROUND One of the most important phenomena in cavity quantum electrodynamics
(cQED) is the so-called strong coupling regime, which appears when the interaction …

Molecular chemistry in cavity strong coupling

K Hirai, JA Hutchison, H Uji-i - Chemical Reviews, 2023 - ACS Publications
The coherent exchange of energy between materials and optical fields leads to strong light–
matter interactions and so-called polaritonic states with intriguing properties, halfway …

Molecular polaritonics: Chemical dynamics under strong light–matter coupling

TE Li, B Cui, JE Subotnik, A Nitzan - Annual review of physical …, 2022 - annualreviews.org
Chemical manifestations of strong light–matter coupling have recently been a subject of
intense experimental and theoretical studies. Here we review the present status of this field …

Vibration-cavity polariton chemistry and dynamics

AD Dunkelberger, BS Simpkins… - Annual review of …, 2022 - annualreviews.org
Molecular polaritons result from light-matter coupling between optical resonances and
molecular electronic or vibrational transitions. When the coupling is strong enough, new …

Theoretical challenges in polaritonic chemistry

J Fregoni, FJ Garcia-Vidal, J Feist - ACS photonics, 2022 - ACS Publications
Polaritonic chemistry exploits strong light–matter coupling between molecules and confined
electromagnetic field modes to enable new chemical reactivities. In systems displaying this …

Visible‐to‐UV Photon Upconversion: Recent Progress in New Materials and Applications

M Uji, TJB Zähringer, C Kerzig… - Angewandte Chemie …, 2023 - Wiley Online Library
Abstract Ultraviolet (UV, λ< 400 nm) light is essential for various photochemical reactions,
but its intensity in the solar spectrum is very low, and light sources that artificially generate …

Quantum information and algorithms for correlated quantum matter

K Head-Marsden, J Flick, CJ Ciccarino… - Chemical …, 2020 - ACS Publications
Discoveries in quantum materials, which are characterized by the strongly quantum-
mechanical nature of electrons and atoms, have revealed exotic properties that arise from …

Energy cascades in donor-acceptor exciton-polaritons observed by ultrafast two-dimensional white-light spectroscopy

M Son, ZT Armstrong, RT Allen, A Dhavamani… - Nature …, 2022 - nature.com
Exciton-polaritons are hybrid states formed when molecular excitons are strongly coupled to
photons trapped in an optical cavity. These systems exhibit many interesting, but not fully …