On surface chemical reactions of free-base and titanyl porphyrins with r-TiO 2 (110): a unified picture

L Schio, D Forrer, M Casarin, A Goldoni… - Physical Chemistry …, 2022 - pubs.rsc.org
In this Perspective we present a comprehensive study of the multiple reaction products of
metal-free porphyrins (2H-Ps) in contact with the rutile TiO2 (110) surface. In the absence of …

Phenylphosphonic Acid on Rutile TiO2(110): Using Theoretically Predicted O 1s Spectra to Identify the Adsorption Binding Modes

A Wolfram, M Muth, J Köbl, A Mölkner… - The Journal of …, 2024 - ACS Publications
We have studied the adsorption of phenylphosphonic acid on rutile TiO2 (110)–(1× 1) using
high-resolution synchrotron-radiation photoelectron spectroscopy and near-edge X-ray …

[HTML][HTML] Role of axial coordination in the adsorption configuration of M (II)-tetraphenylporphyrins (M= Co, Ni, Cu, Zn) on r-TiO2 (110)

L Schio, G Bavdek, C Grazioli, CG Bolaños… - Applied Surface …, 2023 - Elsevier
The efficiency of interfacial charge transfer for photovoltaic and photocatalytic applications of
metal-tetraphenylporphyrins (M-TPPs) on rutile TiO 2 (110) is governed by the molecular …

Adsorption of Phosphonic-Acid-Functionalized Porphyrin Molecules on TiO2(110)

CC Fernández, D Wechsler, TCR Rocha… - The Journal of …, 2019 - ACS Publications
We studied the adsorption geometry and bonding of mono-and tetraphosphonic-acid-
functionalized tetraphenylporphyrin molecules on rutile TiO2 (110) surfaces. The …

Surface structure controls self-metalation: in-situ IR studies of anchored porphyrins on atomically-defined cobalt oxide surfaces

T Wähler, R Schuster, J Libuda - The Journal of Physical …, 2020 - ACS Publications
The functionality of porphyrin/oxide interfaces depends on both the structure of the organic
layer and the metalation of the porphyrin units. While the structure of the porphyrin film is …

Electrospray deposition of structurally complex molecules revealed by atomic force microscopy

A Hinaut, T Meier, R Pawlak, S Feund, R Jöhr, S Kawai… - Nanoscale, 2018 - pubs.rsc.org
Advances in organic chemistry allow the synthesis of large, complex and highly
functionalized organic molecules having potential applications in optoelectronics, molecular …

Adsorption geometry of carboxylic acid functionalized porphyrin molecules on TiO2 (110)

CC Fernandez, D Wechsler, TCR Rocha… - Surface Science, 2019 - Elsevier
Controlling the adsorption geometry of porphyrin molecules on titania surfaces is an
important step in the rational design of molecular devices such as dye-sensitized solar cells …

Self‐Metalation of Anchored Porphyrins on Atomically Defined Cobalt Oxide Surfaces: In situ Studies by Surface Vibrational Spectroscopy

T Wähler, R Schuster, J Libuda - Chemistry–A European …, 2020 - Wiley Online Library
Metalation of anchored porphyrins is essential for their functionality at hybrid interfaces. In
this work, we have studied the anchoring and metalation of a functionalized porphyrin …

Very high temperature tiling of tetraphenylporphyrin on rutile TiO 2 (110)

G Lovat, D Forrer, M Abadia, M Dominguez, M Casarin… - Nanoscale, 2017 - pubs.rsc.org
We demonstrate the thermal stability up to 450° C of a titanium (IV)-porphyrin monolayer
grown on the rutile TiO2 (110) surface. Starting from a film of metal-free tetra-phenyl …

Adsorption and self-assembly of porphyrins on ultrathin CoO films on Ir (100)

F **ang, T Schmitt, M Raschmann… - Beilstein Journal of …, 2020 - beilstein-journals.org
Porphyrins represent a versatile class of molecules, the adsorption behavior of which on
solid surfaces is of fundamental interest due to a variety of potential applications. We …