Crystal engineering: from promise to delivery
D Braga - Chemical Communications, 2023 - pubs.rsc.org
Twenty years ago, I wrote a Chem. Commun. feature article entitled “Crystal Engineering:
where from? Where to?”: an update is in order. In this Highlight I argue that molecular crystal …
where from? Where to?”: an update is in order. In this Highlight I argue that molecular crystal …
Ionic plastic crystals and ionic liquids containing quaternary cations with alkenyl substituents: chemical phase transformations by bromine vapor
Y Nakazono, R Inoue, R Sumitani… - New Journal of Chemistry, 2024 - pubs.rsc.org
Ionic Plastic Crystals (IPCs) and Ionic Liquids (ILs) exhibit intriguing physical properties, but
methods to chemically control their properties remain largely unexplored. To achieve control …
methods to chemically control their properties remain largely unexplored. To achieve control …
Organometallic Ionic Plastic Crystals Incorporating Cationic Half-Sandwich Complexes
R Inoue, R Sumitani, H Honda, D Kuwahara… - Inorganic …, 2024 - ACS Publications
Ionic plastic crystals (IPCs), characterized by nearly spherical molecular ions, exhibit
remarkable solid-state characteristics including high ionic conductivity. However, most IPCs …
remarkable solid-state characteristics including high ionic conductivity. However, most IPCs …
Enabling Superprotonic Phase Transitions in Solid Acids via Supramolecular Complex Formation: The Case of Crown Ethers and Alkali Hydrogen Sulfates
This investigation, combining both structural and spectroscopic analyses, sheds light on the
intricate relationship between conduction properties and the initiation of dynamic motions …
intricate relationship between conduction properties and the initiation of dynamic motions …
Effect of supramolecular complexation of alkali hydrogenselenates with crown ethers and solid-solutions with their hydrogensulfate counterparts on the solid-to-solid …
This study investigates the structural and phase transition characteristics of supramolecular
complexes composed of 18-crown-6 ether and hydrogen selenate (HSeO4−) anions with …
complexes composed of 18-crown-6 ether and hydrogen selenate (HSeO4−) anions with …
Heat Capacities and Role of Defects in Ion Transfer of Quinuclidinium Hexafluorophosphate Plastic Crystal
X Lan, Y Li, X Zhang, W Xu, H Chen, J Liu, H Zhang… - Thermochimica …, 2024 - Elsevier
To study the phase behavior and role of defects in the ion conduction of a well-investigated
plastic crystal electrolyte, we measured the low-temperature heat capacities of …
plastic crystal electrolyte, we measured the low-temperature heat capacities of …
Preparation, Thermal Properties, and Structures of Ionic Crystals with Sandwich and Half-Sandwich Ru Complexes: Exploration of Ionic Plastic Crystals
R Inoue, R Sumitani, T Mochida - Available at SSRN 4756198 - papers.ssrn.com
To investigate organometallic ionic plastic crystals (IPCs), we recently investigated the
phase behavior of salts of cationic sandwich complexes. Here, we synthesized salts …
phase behavior of salts of cationic sandwich complexes. Here, we synthesized salts …