A new class of carbon-rich organometallics. The C3, C4 and C5 metallacumulenes Ru(C) nCR2
D Touchard, PH Dixneuf - Coordination chemistry reviews, 1998 - Elsevier
This review article profiles the advances in ruthenium chemistry for the synthesis of a new
class of organometallic complexes containing conjugated carbon-rich chains. The …
class of organometallic complexes containing conjugated carbon-rich chains. The …
Allenylidene complexes of ruthenium: synthesis, spectroscopy and electron transfer properties
RF Winter, S Záliš - Coordination chemistry reviews, 2004 - Elsevier
This contribution deals with cationic ruthenium allenylidene complexes bearing a large
variety of differently substituted allenylidene ligands attached to the metal. We discuss their …
variety of differently substituted allenylidene ligands attached to the metal. We discuss their …
Indenylidene Complexes of Ruthenium: Optimized Synthesis, Structure Elucidation, and Performance as Catalysts for Olefin Metathesis—Application to the Synthesis …
A Fürstner, O Guth, A Düffels, G Seidel… - … A European Journal, 2001 - Wiley Online Library
An optimized and large scale adaptable synthesis of the ruthenium phenylindenylidene
complex 3 is described which employs commercially available diphenyl propargyl alcohol 5 …
complex 3 is described which employs commercially available diphenyl propargyl alcohol 5 …
Synthesis and characterization of dinuclear metal σ-acetylides and mononuclear metal σ-allenylidenes
A series of dinuclear metal σ-acetylides of the type trans-[Cl (P− P) 2MC⋮ CRC⋮ CM (P− P)
2Cl](M= Fe, Ru, Os; P− P= 1, 2-bis (diphenylphosphino) methane (dppm), 1, 2-bis …
2Cl](M= Fe, Ru, Os; P− P= 1, 2-bis (diphenylphosphino) methane (dppm), 1, 2-bis …
Metal complexes containing cumulenylidene ligands,{LmM} C ( C) n CRR′(n≥ 2)
MI Bruce - Coordination chemistry reviews, 2004 - Elsevier
Metal complexes containing cumulenylidene ligands, {LmM}C(C)nCRR′(n≥2) -
ScienceDirect Skip to main contentSkip to article Elsevier logo Journals & Books Search …
ScienceDirect Skip to main contentSkip to article Elsevier logo Journals & Books Search …
An efficient synthesis of polyynyl and polyynediyl complexes of ruthenium (II)
The fluoride-induced desilylation of trimethylsilyl-substituted alkynes and polyynes and
subsequent reactions with RuCl (PPh3) 2Cp have been used to synthesize complexes …
subsequent reactions with RuCl (PPh3) 2Cp have been used to synthesize complexes …
Novel Ruthenium Allenylidene and Mixed Alkynyl Allenylidene Complexes: Crystal Structure of trans-[(Ph2PCH2CH2PPh2)2Ru(C⋮CPh)(CCCPh2)]PF6
D Touchard, P Haquette, A Daridor, A Romero… - …, 1998 - ACS Publications
cis-RuCl2 (dppe) 2 (1)(dppe= Ph2PCH2CH2PPh2) reacts with propargylic alcohols, HC⋮
CCR1R2OH, and NaPF6 to give a variety of allenylidene complexes trans-[(dppe) 2 (Cl) …
CCR1R2OH, and NaPF6 to give a variety of allenylidene complexes trans-[(dppe) 2 (Cl) …
Mono-and bis-alkynyl ruthenium (II) complexes containing the ferrocenyl moiety; crystal structure of trans-[Ru (C CC5H4FeC5H5) 2 (Ph2PCH2CH2PPh2) 2] and …
C Lebreton, D Touchard, L Le Pichon, A Daridor… - Inorganica chimica …, 1998 - Elsevier
The reaction of RuCl2 (Ph2PCH2CH2PPh2) 2 (RuCl2 (dppe) 2) with the terminal alkynes
FcC CH or FcC C C CH (Fe= ferrocenyl=− C5H4FeC5H5) in the presence of NaPF6 …
FcC CH or FcC C C CH (Fe= ferrocenyl=− C5H4FeC5H5) in the presence of NaPF6 …
Polyazolyl Chelate Chemistry. 7.1 Reactivity of the Complexes [MCl(PPh3)2{HB(pz)3}] (M = Ru, Os; pz = Pyrazol-1-yl)
B Buriez, ID Burns, AF Hill, AJP White… - …, 1999 - ACS Publications
The substitution chemistry of the complex [RuCl (PPh3) 2 {HB (pz) 3}](1) is reported. Treating
1 with the phosphines bis (diphenylphosphino) methane (dppm), 1, 2-bis …
1 with the phosphines bis (diphenylphosphino) methane (dppm), 1, 2-bis …
Syntheses and Chemistry of the Diynyl Complexes M (C⋮ CC⋮ CH)(CO) 3 (η-C5H5)(M= Mo, W): Crystal Structures of W (C⋮ CC⋮ CSiMe3)(CO) 3 (η-C5H5), W {C⋮ …
Reactions of buta-1, 3-diyne with appropriate metal halides, carried out in the presence of
CuI in NHEt2, have given high yields of M (C⋮ CC⋮ CH)(CO) n Cp [M= W (1-W), Mo (1-Mo) …
CuI in NHEt2, have given high yields of M (C⋮ CC⋮ CH)(CO) n Cp [M= W (1-W), Mo (1-Mo) …