Dinuclear metal complexes: multifunctional properties and applications

G Li, D Zhu, X Wang, Z Su, MR Bryce - Chemical Society Reviews, 2020 - pubs.rsc.org
The development of metal complexes for optoelectronic applications is a fertile area of
research. In contrast to the rigorous development of mononuclear metal complexes …

[HTML][HTML] Harnessing high-energy MLCT excited states for artificial photosynthesis

A Cotic, I Ramírez-Wierzbicki, A Cadranel - Coordination Chemistry …, 2024 - Elsevier
Important fractions of the energy absorbed in natural and artificial photosynthetic schemes
are dissipated via fast internal conversion processes. In contrast, chromophores that …

Anti-dissipative strategies toward more efficient solar energy conversion

A Cotic, S Cerfontaine, LD Slep, B Elias… - Journal of the …, 2023 - ACS Publications
In natural and artificial photosynthesis, light absorption and catalysis are separate processes
linked together by exergonic electron transfer. This leads to free energy losses between the …

Photophysics of Ruthenium (II) Complexes with Thiazole π-Extended Dipyridophenazine Ligands

M Kaufmann, C Müller, AA Cullen… - Inorganic …, 2020 - ACS Publications
Transition-metal-based donor–acceptor systems can produce long-lived excited charge-
transfer states by visible-light irradiation. The novel ruthenium (II) polypyridyl type complexes …

Ruthenium Assemblies for CO2 Reduction and H2 Generation: Time Resolved Infrared Spectroscopy, Spectroelectrochemistry and a Photocatalysis Study in …

FJR Cerpentier, J Karlsson, R Lalrempuia… - Frontiers in …, 2021 - frontiersin.org
Two novel supramolecular complexes RuRe ([Ru (dceb) 2 (bpt) Re (CO) 3Cl](PF6)) and
RuPt ([Ru (dceb) 2 (bpt) PtI (H2O)](PF6) 2)[dceb= diethyl (2, 2′-bipyridine)-4, 4 …

New Twist on the Light-Switch Effect: Controlling the Fate of Excited States with pH in a 4-Hydroxy-thiazol-extended Ruthenium (II) Dppz Complex

C Müller, M Kaufmann, MP Brandon… - The Journal of …, 2023 - ACS Publications
We present a pH-dependent study of the excited state dynamics of a novel Ru complex
bearing a 4-hydroxy thiazol-substituted dppz (dipyridophenazine) ligand (RuTzOH) and its …

A Time-Resolved Spectroscopic Investigation of a Novel BODIPY Copolymer and Its Potential Use as a Photosensitiser for Hydrogen Evolution

AA Cullen, K Heintz, L O'Reilly, C Long, A Heise… - Frontiers in …, 2020 - frontiersin.org
A novel 4, 4-difuoro-4-bora-3a, 4a-diaza-s-indacene (BODIPY) copolymer with
diethynylbenzene has been synthesised, and its ability to act as a photosensitiser for the …

Comparing Activity and Effectiveness of (Ru/Pd),(Ru/Pt) Photocatalysts for Hydrogen Generation, Photochemical Reaction with HPLC

HM Younis - The Scientific Journal of University of Benghazi, 2020 - journals.uob.edu.ly
In this contribution recent developments in the design and application of Ru/Pd, Ru/Pt
photocatalysts for the generation of hydrogen via intramolecular processes are assessed …