Polynuclear NiII and MnII azido bridging complexes. Structural trends and magnetic behavior

J Ribas, A Escuer, M Monfort, R Vicente… - Coordination Chemistry …, 1999 - Elsevier
The azide anion is a good bridging ligand for divalent metal ions, mainly CuII, NiII and MnII.
It may give end-to-end (1, 3) or end-on (1, 1) coordination modes. As a general trend, the 1 …

Molecular ferromagnets

VI Ovcharenko, RZ Sagdeev - Russian chemical reviews, 1999 - pubs.rsc.org
Molecular ferromagnets Page 1 Abstract. The state-of-the-art, achievements, problems and
prospects of an actively develo** area of supramolecular chemistry, viz., the design of …

Constructing magnetic molecular solids by employing three-atom ligands as bridges

XY Wang, ZM Wang, S Gao - Chemical Communications, 2008 - pubs.rsc.org
The combination of some three-atom bridges with paramagnetic 3d transition metal ions
results in the systematic isolation of molecular magnetic materials, ranging from single …

Asymmetric Conjugate Addition of Azide to α,β‐Unsaturated Carbonyl Compounds Catalyzed by Simple Peptides

TE Horstmann, DJ Guerin, SJ Miller - Angewandte Chemie, 2000 - Wiley Online Library
Einfache Tripeptide A bilden asymmetrische Katalysatoren für die enantioselektive 1, 4-
Addition von Azid-Ionen an Enoate wie 1. Man erhält dabei unter milden …

Coexistence of spin-canting, metamagnetism, and spin-flop in a (4, 4) layered manganese azide polymer

XY Wang, L Wang, ZM Wang, G Su… - Chemistry of …, 2005 - ACS Publications
A novel molecule-based magnetic polymer Mn (N3) 2 (btr) 2 1 (btr= 4, 4 '-bi-1, 2, 4-triazole)
was synthesized and characterized crystallographically and magnetically. 1 crystallizes in …

Synthesis, structural characterization, magnetic behavior, and single crystal EPR spectra of three new one-dimensional manganese azido systems with FM, alternating …

MAM Abu-Youssef, A Escuer, D Gatteschi… - Inorganic …, 1999 - ACS Publications
Reaction of sodium azide with manganese (II) and pyridine derivatives such as 2-bzpy, 3-
bzpy, and 3, 5lut (2-benzoylpyridine, 3-benzoylpyridine, and 3, 5-dimethylpyridine …

Synthesis, Structure, and Magnetic Properties of Mn(salpn)N3, a Helical Polymer, and Fe(salpn)N3, a Ferromagnetically Coupled Dimer (salpnH2 = N,N'-bis …

KR Reddy, MV Rajasekharan… - Inorganic chemistry, 1998 - ACS Publications
The preparation, crystal structures, and variable temperature magnetic susceptibility data
are presented for two azido-bridged Schiff base complexes of Mn (III) and Fe (III). Mn (salpn) …

Azide-Bridged One-Dimensional MnIII Polymers:  Effects of Side Group of Schiff Base Ligands on Structure and Magnetism

M Yuan, F Zhao, W Zhang, ZM Wang, S Gao - Inorganic chemistry, 2007 - ACS Publications
By changing ancillary tetradentate Schiff base ligands (L), two new one-dimensional azide-
bridged manganese (III) coordination complexes [MnIII (L)(μ1, 3-N3)] n [L= 5-Fsalen (1), 5 …

Synthesis, Structural Characterisation, and Monte Carlo Simulation of the Magnetic Properties of the 3D‐Stacked Honeycomb Csn [{Mn (N3) 3} n] and the Irregular …

MAS Goher, J Cano, Y Journaux… - … A European Journal, 2000 - Wiley Online Library
Two new polymeric manganese‐azido systems with formula Csn [{Mn (N3) 3} n](1) and [{N
(C2H5) 4} n][{Mn2 (N3) 5 (H2O)} n](2) were synthesised and structurally characterised …

Synthesis and Structural Characterization of [Mn(ethyl isonicotinate)2(N3)2]n, a Two-Dimensional Alternating Ferromagnetic−Antiferromagnetic Compound …

A Escuer, R Vicente, MAS Goher… - Inorganic …, 1996 - ACS Publications
Three compounds with formula [Mn (L) 2 (N3) 2] n, in which L is 4-acpy= 4-acetylpyridine (1),
Etinc= ethyl isonicotinate (2), and py= pyridine (3), have been studied from the magnetic …