Understanding polaritonic chemistry from ab initio quantum electrodynamics
In this review, we present the theoretical foundations and first-principles frameworks to
describe quantum matter within quantum electrodynamics (QED) in the low-energy regime …
describe quantum matter within quantum electrodynamics (QED) in the low-energy regime …
Cavity-enhanced energy transport in molecular systems
Molecules are the building blocks of all of nature's functional components, serving as the
machinery that captures, stores and releases energy or converts it into useful work …
machinery that captures, stores and releases energy or converts it into useful work …
From enhanced diffusion to ultrafast ballistic motion of hybrid light–matter excitations
Transport of excitons and charge carriers in molecular systems can be enhanced by
coherent coupling to photons, giving rise to the formation of hybrid excitations known as …
coherent coupling to photons, giving rise to the formation of hybrid excitations known as …
Vibration-cavity polariton chemistry and dynamics
Molecular polaritons result from light-matter coupling between optical resonances and
molecular electronic or vibrational transitions. When the coupling is strong enough, new …
molecular electronic or vibrational transitions. When the coupling is strong enough, new …
Swinging between shine and shadow: Theoretical advances on thermally activated vibropolaritonic chemistry
Polariton chemistry has emerged as an appealing branch of synthetic chemistry that
promises mode selectivity and a cleaner approach to kinetic control. Of particular interest are …
promises mode selectivity and a cleaner approach to kinetic control. Of particular interest are …
Cavity-enabled enhancement of ultrafast intramolecular vibrational redistribution over pseudorotation
Vibrational strong coupling (VSC) between molecular vibrations and microcavity photons
yields a few polaritons (light-matter modes) and many dark modes (with negligible photonic …
yields a few polaritons (light-matter modes) and many dark modes (with negligible photonic …
[HTML][HTML] Reproducibility of cavity-enhanced chemical reaction rates in the vibrational strong coupling regime
One of the most exciting and debated aspects of polariton chemistry is the possibility that
chemical reactions can be catalyzed by vibrational strong coupling (VSC) with confined …
chemical reactions can be catalyzed by vibrational strong coupling (VSC) with confined …
Catalysis by dark states in vibropolaritonic chemistry
Collective strong coupling between a disordered ensemble of N localized molecular
vibrations and a resonant optical cavity mode gives rise to two polariton and N-1≫ 2 dark …
vibrations and a resonant optical cavity mode gives rise to two polariton and N-1≫ 2 dark …
Inherent promotion of ionic conductivity via collective vibrational strong coupling of water with the vacuum electromagnetic field
T Fukushima, S Yoshimitsu… - Journal of the American …, 2022 - ACS Publications
Hydrogen bonding interactions among water molecules play a critical role in chemical
reactivity, dynamic proton mobility, static dielectric behavior, and the thermodynamic …
reactivity, dynamic proton mobility, static dielectric behavior, and the thermodynamic …
Mode-Specific Chemistry through Vibrational Strong Coupling (or A Wish Come True)
Vibrational strong coupling offers newfound potential to affect chemical processes and
represents a wholly new approach to catalysis. While this presents extraordinary …
represents a wholly new approach to catalysis. While this presents extraordinary …