Understanding polaritonic chemistry from ab initio quantum electrodynamics

M Ruggenthaler, D Sidler, A Rubio - Chemical Reviews, 2023 - ACS Publications
In this review, we present the theoretical foundations and first-principles frameworks to
describe quantum matter within quantum electrodynamics (QED) in the low-energy regime …

Cavity-enhanced energy transport in molecular systems

G Sandik, J Feist, FJ García-Vidal, T Schwartz - Nature Materials, 2024 - nature.com
Molecules are the building blocks of all of nature's functional components, serving as the
machinery that captures, stores and releases energy or converts it into useful work …

From enhanced diffusion to ultrafast ballistic motion of hybrid light–matter excitations

M Balasubrahmaniyam, A Simkhovich, A Golombek… - Nature Materials, 2023 - nature.com
Transport of excitons and charge carriers in molecular systems can be enhanced by
coherent coupling to photons, giving rise to the formation of hybrid excitations known as …

Vibration-cavity polariton chemistry and dynamics

AD Dunkelberger, BS Simpkins… - Annual review of …, 2022 - annualreviews.org
Molecular polaritons result from light-matter coupling between optical resonances and
molecular electronic or vibrational transitions. When the coupling is strong enough, new …

Swinging between shine and shadow: Theoretical advances on thermally activated vibropolaritonic chemistry

JA Campos-Gonzalez-Angulo, YR Poh, M Du… - The Journal of …, 2023 - pubs.aip.org
Polariton chemistry has emerged as an appealing branch of synthetic chemistry that
promises mode selectivity and a cleaner approach to kinetic control. Of particular interest are …

Cavity-enabled enhancement of ultrafast intramolecular vibrational redistribution over pseudorotation

TT Chen, M Du, Z Yang, J Yuen-Zhou, W **ong - Science, 2022 - science.org
Vibrational strong coupling (VSC) between molecular vibrations and microcavity photons
yields a few polaritons (light-matter modes) and many dark modes (with negligible photonic …

[HTML][HTML] Reproducibility of cavity-enhanced chemical reaction rates in the vibrational strong coupling regime

MV Imperatore, JB Asbury, NC Giebink - The Journal of Chemical …, 2021 - pubs.aip.org
One of the most exciting and debated aspects of polariton chemistry is the possibility that
chemical reactions can be catalyzed by vibrational strong coupling (VSC) with confined …

Catalysis by dark states in vibropolaritonic chemistry

M Du, J Yuen-Zhou - Physical Review Letters, 2022 - APS
Collective strong coupling between a disordered ensemble of N localized molecular
vibrations and a resonant optical cavity mode gives rise to two polariton and N-1≫ 2 dark …

Inherent promotion of ionic conductivity via collective vibrational strong coupling of water with the vacuum electromagnetic field

T Fukushima, S Yoshimitsu… - Journal of the American …, 2022 - ACS Publications
Hydrogen bonding interactions among water molecules play a critical role in chemical
reactivity, dynamic proton mobility, static dielectric behavior, and the thermodynamic …

Mode-Specific Chemistry through Vibrational Strong Coupling (or A Wish Come True)

BS Simpkins, AD Dunkelberger… - The Journal of Physical …, 2021 - ACS Publications
Vibrational strong coupling offers newfound potential to affect chemical processes and
represents a wholly new approach to catalysis. While this presents extraordinary …