Most homogeneous catalysis relies on the design of metal complexes to trap and convert
substrates or small molecules to value‐added products. Organometallic lanthanide …

The chemistry of actinide (An) and rare-earth metal (Ln and group 3) complexes featuring
multiple bonding interactions with main-group fragments has witnessed an enormous …

While β-diketiminate (BDI or 'nacnac') ligands have been widely adopted to stabilize a wide
range of metal ions in multiple oxidation states and coordination numbers, in several …

Despite widespread applications of tetravalent cerium compounds in organic synthesis and
catalysis, the coordination and organometallic chemistry of cerium (IV) complexes has not …

Complexes featuring lanthanide–ligand multiple bonds are rare and highly reactive. They
are important synthetic targets to understand 4f/5d-bonding in comparison to d-block and …

Conspectus Research into transition metal complexes bearing multiply bonded main-group
ligands has developed into a thriving and fruitful field over the past half century. These …

The reaction of the base‐free terminal thorium imido complex [{η5‐1, 2, 4‐(Me3C) 3C5H2}
2Th N (p‐tolyl)](1) with p‐azidotoluene yielded irreversibly the …

The formation of actinide–transition metal heterobimetallics mediated by a terminal actinide
imido complex was comprehensively studied. The reaction of the thorium imido complex [(η5 …

We report a metathesis reaction in which a nitrene fragment from an isocyanide ligand is
exchanged with a nitrene fragment of an imido ligand in a series of niobium bis (imido) …

By using the β-diketiminato ligands bearing pendant nitrogen or oxygen donors, a series of
rare-earth metal complexes containing reactive metal-bound functionalities have been …