Recognition in the domain of molecular chirality: from noncovalent interactions to separation of enantiomers
It is not a coincidence that both chirality and noncovalent interactions are ubiquitous in
nature and synthetic molecular systems. Noncovalent interactivity between chiral molecules …
nature and synthetic molecular systems. Noncovalent interactivity between chiral molecules …
Chiral recognition in separation science–an update
GKE Scriba - Journal of Chromatography a, 2016 - Elsevier
Stereospecific recognition of chiral molecules is an important issue in various aspects of life
sciences and chemistry including analytical separation sciences. The basis of analytical …
sciences and chemistry including analytical separation sciences. The basis of analytical …
Noncovalent interactions in high-performance liquid chromatography enantioseparations on polysaccharide-based chiral selectors
Designed more than thirty years ago in order to improve and maximize the discrimination
capability of native polysaccharides, cellulose-and amylose-based selectors have shown …
capability of native polysaccharides, cellulose-and amylose-based selectors have shown …
Engineering an alcohol dehydrogenase with enhanced activity and stereoselectivity toward diaryl ketones: reduction of steric hindrance and change of the …
K Wu, Z Yang, X Meng, R Chen, J Huang… - Catalysis Science & …, 2020 - pubs.rsc.org
Steric hindrance in the binding pocket of an alcohol dehydrogenase (ADH) has a great
impact on its activity and stereoselectivity simultaneously. Due to the subtle structural …
impact on its activity and stereoselectivity simultaneously. Due to the subtle structural …
Stereoselective processes based on σ-hole interactions
The σ-hole interaction represents a noncovalent interaction between atoms with σ-hole (s)
on their surface (such as halogens and chalcogens) and negative sites. Over the last …
on their surface (such as halogens and chalcogens) and negative sites. Over the last …
Homochiral metal–organic frameworks and their application in chromatography enantioseparations
The last frontier in the chiral stationary phases (CSPs) field for chromatography
enantioseparations is represented by homochiral metal-organic frameworks (MOFs), a class …
enantioseparations is represented by homochiral metal-organic frameworks (MOFs), a class …
Disubstituted ferrocenyl iodo-and chalcogenoalkynes as chiral halogen and chalcogen bond donors
Asymmetric catalysis based on halogen and chalcogen bonds (XB and ChB) is in its infancy,
and the search for new chiral XB and ChB donors represents a crucial step toward its …
and the search for new chiral XB and ChB donors represents a crucial step toward its …
[HTML][HTML] Unravelling dispersion forces in liquid-phase enantioseparation. Part I: Impact of ferrocenyl versus phenyl groups
Background Highly ordered chiral secondary structures as well as multiple (tunable)
recognition sites are the keys to success of polysaccharide carbamate-based chiral …
recognition sites are the keys to success of polysaccharide carbamate-based chiral …
Halogen bond in separation science: A critical analysis across experimental and theoretical results
The halogen bond (XB) is a noncovalent interaction involving a halogen acting as
electrophile and a Lewis base. In the last decades XB has found practical application in …
electrophile and a Lewis base. In the last decades XB has found practical application in …
Recent studies of docking and molecular dynamics simulation for liquid‐phase enantioseparations
Liquid‐phase enantioseparations have been fruitfully applied in several fields of science.
Various applications along with technical and theoretical advancements contributed to …
Various applications along with technical and theoretical advancements contributed to …