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Decoding chemical and physical processes driving plasmonic photocatalysis using surface-enhanced Raman spectroscopies
Conspectus In order to mitigate the advancing effects of environmental pollution and climate
change, immediate action is needed on social, political, and industrial fronts. One segment …
change, immediate action is needed on social, political, and industrial fronts. One segment …
Nanoscale and ultrafast in situ techniques to probe plasmon photocatalysis
Plasmonic photocatalysis uses the light-induced resonant oscillation of free electrons in a
metal nanoparticle to concentrate optical energy for driving chemical reactions. By altering …
metal nanoparticle to concentrate optical energy for driving chemical reactions. By altering …
Investigation of the mechanisms of plasmon-mediated photocatalysis: synergistic contribution of near-field and charge transfer effects
Plasmonic photocatalysis is an attractive way to drive and enhance chemical reactions. The
relative importance of thermal and non-thermal effects in driving the reaction is still under …
relative importance of thermal and non-thermal effects in driving the reaction is still under …
Photochemical oxidation of substrate water analogs and halides by Photosystem II
J Shin, J Kanyo, RJ Debus… - Advanced Energy …, 2024 - Wiley Online Library
Photosystem II (PSII) is a multi‐subunit protein‐pigment complex with diverse redox‐active
cofactors, which enabled the biological availability of O2 on Earth. The substrate specificity …
cofactors, which enabled the biological availability of O2 on Earth. The substrate specificity …
Plasmon-driven photocatalytic molecular transformations on metallic nanostructure surfaces: mechanistic insights gained from plasmon-enhanced Raman …
Optically excited plasmonic nanostructures exhibit unique capabilities to catalyze interfacial
chemical transformations of molecules adsorbed on their surfaces in a regioselective …
chemical transformations of molecules adsorbed on their surfaces in a regioselective …
Molecular optomechanics induced hybrid properties in soft materials filled plasmonic nanocavities
The optomechanical interaction between nanocavity plasmons and molecular vibrations can
result in interfacial phenomena that can be tailored for sensing and photocatalytic …
result in interfacial phenomena that can be tailored for sensing and photocatalytic …
Hot-hole-induced molecular scissoring: a case study of plasmon-driven decarboxylation of aromatic carboxylates
Optically excited plasmonic nanostructures may function as molecular scissors with unique
capabilities to cleave specific chemical bonds in molecular adsorbates through either …
capabilities to cleave specific chemical bonds in molecular adsorbates through either …
Switching a plasmon-driven reaction mechanism from charge transfer to adsorbate electronic excitation using surface ligands
H Kookhaee, TE Tesema… - The Journal of Physical …, 2020 - ACS Publications
Understanding photocatalytic reaction conditions that selectively leads to a desired product
on metal surfaces is a longstanding research problem in heterogeneous catalysis. Here …
on metal surfaces is a longstanding research problem in heterogeneous catalysis. Here …
Modulating the electron affinity of small bipyridyl molecules on single gold nanoparticles for plasmon-driven electron transfer
EA Sprague-Klein, R Ho-Wu, D Nguyen… - The Journal of …, 2021 - ACS Publications
Develo** controlled platforms for plasmon-driven chemistry is of great importance in
catalytic reactions at the nanoscale. We report anion radical formation for five bipyridyl …
catalytic reactions at the nanoscale. We report anion radical formation for five bipyridyl …
Quantifying the ultrafast and steady-state molecular reduction potential of a plasmonic photocatalyst
CL Warkentin, RR Frontiera - Proceedings of the National Academy of …, 2023 - pnas.org
Plasmonic materials are promising photocatalysts as they are well suited to convert light into
hot carriers and heat. Hot electron transfer is suggested as the driving force in many …
hot carriers and heat. Hot electron transfer is suggested as the driving force in many …