[HTML][HTML] Single-Molecule Magnets: From Mn12-ac to dysprosium metallocenes, a travel in time

A Zabala-Lekuona, JM Seco, E Colacio - Coordination Chemistry Reviews, 2021 - Elsevier
The discovery of the first Single-Molecule Magnet, Mn12-ac, in 1993 changed the
perspective of how information can be stored. The current bit, occupying few hundreds of …

Metal–metal bond in lanthanide single-molecule magnets

Z Zhu, J Tang - Chemical Society Reviews, 2022 - pubs.rsc.org
Lanthanide (Ln) compounds represent a unique chemical platform for develo** high-
temperature single-molecule magnets (SMMs). The shift in research focus from increasing …

Emerging trends on designing high-performance dysprosium (III) single-molecule magnets

TG Ashebr, H Li, X Ying, XL Li, C Zhao, S Liu… - ACS Materials …, 2022 - ACS Publications
The present prospect of single-molecule magnets (SMMs) research is more appealing after
the detection of magnetic remanence above liquid-nitrogen temperatures. From the current …

Unraveling the contributions to spin–lattice relaxation in kramers single-molecule magnets

S Mondal, A Lunghi - Journal of the American Chemical Society, 2022 - ACS Publications
The study of how spin interacts with lattice vibrations and relaxes to equilibrium provides
unique insights into its chemical environment and the relation between electronic structure …

Spin dynamics in single-molecule magnets and molecular qubits

D Aravena, E Ruiz - Dalton Transactions, 2020 - pubs.rsc.org
Over recent decades, much effort has been made to lengthen spin relaxation/decoherence
times of single-molecule magnets and molecular qubits by following different chemical …

High performance single-molecule magnets, Orbach or Raman relaxation suppression?

A Castro-Alvarez, Y Gil, L Llanos… - Inorganic Chemistry …, 2020 - pubs.rsc.org
The current figure of merit to evaluate Single Molecule Magnet (SMM) performance is the
blocking temperature (TB). The best SMMs show TB values close to liquid nitrogen boiling …

The future of polyoxymetalates for biological and chemical apllications

MJW Budych, K Staszak, A Bajek, F Pniewski… - Coordination Chemistry …, 2023 - Elsevier
This paper reports the most interesting applications of polyoxometalates (POMs) over the
last five years, highlighting the relationship between their complex nature, properties, and …

A conjugated Schiff-base macrocycle weakens the transverse crystal field of air-stable dysprosium single-molecule magnets

S Liu, Y Gil, C Zhao, J Wu, Z Zhu, XL Li… - Inorganic Chemistry …, 2022 - pubs.rsc.org
Self-condensation of bifunctional 8-aminoquinoline-2-carbaldehyde templated by
dysprosium (III) ions followed by the replacement of axial ligands with triphenylsilanol in the …

Understanding the magnetic anisotropy for linear sandwich [Er (COT)]+-based compounds: a theoretical investigation

MM Ding, T Shang, R Hu, YQ Zhang - Dalton Transactions, 2022 - pubs.rsc.org
A series of linear sandwich single-ion magnets containing [Er (COT)]+ fragment were
selected to probe the magneto-structural correlations using ab initio methods. For prolate …

A method to predict both the relaxation time of quantum tunneling of magnetization and the effective barrier of magnetic reversal for a Kramers single-ion magnet

B Yin, CC Li - Physical Chemistry Chemical Physics, 2020 - pubs.rsc.org
In this work, a theoretical method for the prediction of both the relaxation time of quantum
tunneling of magnetization (τQTM) and the effective barrier of magnetic reversal (Ueff) is …