Electrochemical C–N coupling of CO 2 and nitrogenous small molecules for the electrosynthesis of organonitrogen compounds

X Peng, L Zeng, D Wang, Z Liu, Y Li, Z Li… - Chemical Society …, 2023 - pubs.rsc.org
Electrochemical C–N coupling reactions based on abundant small molecules (such as CO2
and N2) have attracted increasing attention as a new “green synthetic strategy” for the …

Strategies and mechanisms of metal–ligand cooperativity in first-row transition metal complex catalysts

MR Elsby, RT Baker - Chemical Society Reviews, 2020 - pubs.rsc.org
The use of metal–ligand cooperation (MLC) by transition metal bifunctional catalysts has
emerged at the forefront of homogeneous catalysis science. Specially designed ligands can …

Hydride transfer reactions catalyzed by cobalt complexes

W Ai, R Zhong, X Liu, Q Liu - Chemical reviews, 2018 - ACS Publications
Cobalt has become increasingly attractive in homogeneous catalysis because of its unique
characteristics and outstanding catalytic performance in addition to being cheap and earth …

N-heterocyclic carbene complexes of copper, nickel, and cobalt

AA Danopoulos, T Simler, P Braunstein - Chemical reviews, 2019 - ACS Publications
The emergence of N-heterocyclic carbenes as ligands across the Periodic Table had an
impact on various aspects of the coordination, organometallic, and catalytic chemistry of the …

Cobalt–N-heterocyclic carbene complexes in catalysis

SS Bera, M Szostak - ACS catalysis, 2022 - ACS Publications
Cobalt–N-heterocyclic carbene (NHC) complexes have emerged as an attractive class of 3d
transition metal catalysts for a broad range of chemical processes, including cross-coupling …

Cobalt complexes as an emerging class of catalysts for homogeneous hydrogenations

W Liu, B Sahoo, K Junge, M Beller - Accounts of Chemical …, 2018 - ACS Publications
Conspectus Catalytic hydrogenation using molecular hydrogen represents a green and
practical approach for reductions of all kinds of organic chemicals. Traditionally, in the …

Cobalt–pincer complexes in catalysis

K Junge, V Papa, M Beller - Chemistry–A European Journal, 2019 - Wiley Online Library
Non‐noble metal catalysts based on pincer type compounds are of special interest for
organometallic chemistry and organic synthesis. Next to iron and manganese, currently …

Unmasking the ligand effect in manganese-catalyzed hydrogenation: mechanistic insight and catalytic application

Y Wang, L Zhu, Z Shao, G Li, Y Lan… - Journal of the American …, 2019 - ACS Publications
Manganese-catalyzed hydrogenation reactions have attracted broad interest since the first
report in 2016. Among the reported catalytic systems, Mn catalysts supported by tridentate …

[HTML][HTML] Electrochemical reduction of acetonitrile to ethylamine

R **a, D Tian, S Kattel, B Hasa, H Shin, X Ma… - Nature …, 2021 - nature.com
Electrifying chemical manufacturing using renewable energy is an attractive approach to
reduce the dependence on fossil energy sources in chemical industries. Primary amines are …

Direct synthesis of benzimidazoles by dehydrogenative coupling of aromatic diamines and alcohols catalyzed by cobalt

P Daw, Y Ben-David, D Milstein - ACS Catalysis, 2017 - ACS Publications
Herein, we present the base-metal-catalyzed dehydrogenative coupling of primary alcohols
and aromatic diamines to selectively form functionalized 2-substituted benzimidazoles …