Design of collective motions from synthetic molecular switches, rotors, and motors
Precise control over molecular movement is of fundamental and practical importance in
physics, biology, and chemistry. At nanoscale, the peculiar functioning principles and the …
physics, biology, and chemistry. At nanoscale, the peculiar functioning principles and the …
[HTML][HTML] Artificial molecular machines
The widespread use of molecular machines in biology has long suggested that great
rewards could come from bridging the gap between synthetic molecular systems and the …
rewards could come from bridging the gap between synthetic molecular systems and the …
Synthetic molecular motors and mechanical machines
The widespread use of controlled molecular‐level motion in key natural processes suggests
that great rewards could come from bridging the gap between the present generation of …
that great rewards could come from bridging the gap between the present generation of …
Artificial molecular rotors
To many, periodic mechanical conformational motion of molecules is mesmerizing to a
degree that is difficult to explain rationally: It is almost as hard to stop watching an image of …
degree that is difficult to explain rationally: It is almost as hard to stop watching an image of …
(Nano) mechanical motion triggered by metal coordination: from functional devices to networked multicomponent catalytic machinery
A look at the elegance and efficiency of biological machines readily reveals that Nature
masters the full gamut of chemical interactions to compose masterpieces of the living world …
masters the full gamut of chemical interactions to compose masterpieces of the living world …
Metallosupramolecular architectures obtained from poly-N-heterocyclic carbene ligands
N Sinha, FE Hahn - Accounts of Chemical Research, 2017 - ACS Publications
Conspectus Over the past two decades, self-assembly of supramolecular architectures has
become a field of intensive research due to the wide range of applications for the resulting …
become a field of intensive research due to the wide range of applications for the resulting …
Beyond platonic: how to build metal–organic polyhedra capable of binding low-symmetry, information-rich molecular cargoes
The field of metallosupramolecular chemistry has advanced rapidly in recent years. Much
work in this area has focused on the formation of hollow self-assembled metal-organic …
work in this area has focused on the formation of hollow self-assembled metal-organic …
Twisted pentagonal prisms: AgnL2 metal-organic pillars
The structures of hierarchically assembled supramolecular architectures are dictated
characteristically by the encoded symmetries and geometries of the corresponding building …
characteristically by the encoded symmetries and geometries of the corresponding building …
Coordination chemistry strategies for dynamic helicates: time-programmable chirality switching with labile and inert metal helicates
H Miyake, H Tsukube - Chemical Society Reviews, 2012 - pubs.rsc.org
'Chirality switching'is one of the most important chemical processes controlling many
biological systems. DNAs and proteins often work as time-programmed functional helices, in …
biological systems. DNAs and proteins often work as time-programmed functional helices, in …
Structural flexibility in metal-organic cages
AE Martín Díaz, JEM Lewis - Frontiers in Chemistry, 2021 - frontiersin.org
Metal-organic cages (MOCs) have emerged as a diverse class of molecular hosts with
potential utility across a vast spectrum of applications. With advances in single-crystal X-ray …
potential utility across a vast spectrum of applications. With advances in single-crystal X-ray …