Unfolding the chemistry of FOX-7: Unique energetic material and precursor with numerous possibilities

S Banik, AK Yadav, P Kumar, VD Ghule… - Chemical Engineering …, 2022 - Elsevier
FOX-7 demonstrates a fascinating explosophoric motif with a unique combination of
detonation performance and stability. Unlike classical explosives, such as TNT, TATB, and …

Fluorine‐Containing Functional Group‐Based Energetic Materials

Z Guo, Q Yu, Y Chen, J Liu, T Li, Y Peng… - The Chemical …, 2023 - Wiley Online Library
Molecules featuring fluorine‐containing functional groups exhibit outstanding properties with
high density, low sensitivity, excellent thermal stability, and good energetic performance due …

Introduction of energetic bis-1, 2, 4-triazoles bridges: A strategy towards advanced heat resistant explosives

T Yan, J Ma, H Yang, G Cheng - Chemical Engineering Journal, 2022 - Elsevier
Over the last few decades, the research for energetic materials with ultrahigh heat resistance
and good energy level has been a highly severe challenge. In this study, a novel heat …

FOX-7 based nitrogen rich green energetic salts: Synthesis, characterization, propulsive and detonation performance

S Lal, RJ Staples, MS Jean'ne - Chemical Engineering Journal, 2023 - Elsevier
Abstract New 1, 1-diamino-2, 2-dinitroethene (FOX-7)-based energetic salts are reported in
this study. A variety of bases including hydrazine, hydroxylamine, ammonia, amino …

FOX-7 derived nitramines: Novel propellants and oxidizers for solid rocket propulsion

S Lal, RJ Staples, MS Jean'ne - Chemical Engineering Journal, 2023 - Elsevier
A variety of amine derivatives was found to react with FOX-7 to give triazine derivatives,
which upon nitration gave rearranged nitramines in good to excellent yields. The structures …

Halogen bonding (CF··· X) and its effect on creating ideal insensitive energetic materials

Y Kang, Y Dong, Y Liu, H Gao, Y Wang… - Chemical Engineering …, 2022 - Elsevier
Abstract A series of 3-trifluoromethyl-6-amine-1, 2, 4-triazolo [4, 3-b][1, 2, 4, 5] tetrazine-
based energetic materials were efficiency synthesized and fully characterized with IR …

Raman and Synchrotron X-ray Diffraction Studies of Cd2(C2H6N6)4(NO3)·4H2O under High Pressures

J Ding, Z Pu, J Jiang, P Zhu, H Zhu - The Journal of Physical …, 2024 - ACS Publications
Cd2 (C2H6N6) 4 (NO3) 4· H2O (CdHATr), a triazole-based energetic compound, was
selected for high-pressure research. Employing in situ Raman scattering and synchrotron …

[HTML][HTML] Obtaining advanced insensitive energetic materials by regioselectively introducing N-oxide groups onto 6-trifluoromethyl-1, 2, 4, 5-tetrazine-3-amine

Q Liu, H Wang, Y Kang, P Yu, M Yuan, H Gao - Energetic Materials …, 2023 - Elsevier
Three N-oxide energetic compounds were selectively obtained from 6-trifluoromethyl-1, 2, 4,
5-tetrazin-3-amine using four kinds of oxidation systems. Their structures were verified …

Recent developments in the chemistry of 1H-and 4H-1, 2, 4-triazoles

AA Abbas, KM Dawood - Advances in Heterocyclic Chemistry, 2023 - Elsevier
Abstract 1H-and 4H-1, 2, 4-Triazoles have wide potent biological applications; therefore,
develo** new synthetic routes for such interesting scaffolds is of great importance. The …

One-step synthesis of 6-amino-5-nitro-2-(trinitromethyl)-pyrimidin-4 (3H)-one as potential energetic material

Y Li, H **a, S Song, K Wang, Q Zhang - Inorganic Chemistry …, 2023 - Elsevier
The first trinitromethyl-substituted pyrimidine derivative (3) was synthesized by direct
nitration of its 2-methylpyrimidine precursor, and its structure was thoroughly characterized …