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Porphyrins as building blocks for single-molecule devices
Direct measurement of single-molecule electrical transparency by break junction
experiments has become a major field of research over the two last decades. This review …
experiments has become a major field of research over the two last decades. This review …
A review of oligo (arylene ethynylene) derivatives in molecular junctions
Oligo (arylene ethynylene)(OAE) derivatives are the “workhorse” molecules of molecular
electronics. Their ease of synthesis and flexibility of functionalisation mean that a diverse …
electronics. Their ease of synthesis and flexibility of functionalisation mean that a diverse …
Mechanical conductance tunability of a porphyrin–cyclophane single-molecule junction
The possibility to study quantum interference phenomena at ambient conditions is an
appealing feature of molecular electronics. By connecting two porphyrins in a cofacial …
appealing feature of molecular electronics. By connecting two porphyrins in a cofacial …
Benchmarking break-junction techniques: electric and thermoelectric characterization of naphthalenophanes
Break-junction techniques provide the possibility to study electric and thermoelectric
properties of single-molecule junctions in great detail. These techniques rely on the same …
properties of single-molecule junctions in great detail. These techniques rely on the same …
Mechanical compression in cofacial porphyrin cyclophane pincers
Intra-and intermolecular interactions are dominating chemical processes, and their
concerted interplay enables complex nonequilibrium states like life. While the responsible …
concerted interplay enables complex nonequilibrium states like life. While the responsible …
Tuning the aromatic backbone twist in dipyrrolonaphthyridinediones
This communication describes the photophysical behavior of three analogs of cyclophane
bearing the dipyrrolonaphthyridinedione (DPND) core. In these molecules, intersystem …
bearing the dipyrrolonaphthyridinedione (DPND) core. In these molecules, intersystem …
Design and Synthesis of Multipath Compact Cyclophanes for Quantum Interference Studies
SL Heim, A Gallego, V Bertozzi… - European Journal of …, 2024 - Wiley Online Library
To investigate interference phenomena and conductance properties in mechanically
controlled break junctions (MCBJs), macrocycles 1 and 2 (BMCs: for BenzeneMacroCycles) …
controlled break junctions (MCBJs), macrocycles 1 and 2 (BMCs: for BenzeneMacroCycles) …
[HTML][HTML] Controlling quantum interference patterns in redox-active rings
The ability to create molecules, which exhibit tunable and unique conductive properties is a
key requirement for the development of future generation devices. Towards this concept, we …
key requirement for the development of future generation devices. Towards this concept, we …