Topology matters: Conformation and microscopic dynamics of ring polymers

M Kruteva, J Allgaier, D Richter - Macromolecules, 2023 - ACS Publications
Ring polymers have fascinated theorists, simulators, and experimentalists as they are the
simplest polymer without ends, giving rise to important topology related properties. We …

Regulating polysulfide diffusion and deposition via rational design of core–shell active materials in Li–S batteries

L Feng, P Yu, X Fu, ZM Zhang, K Davey, Y Wang… - ACS …, 2022 - ACS Publications
Polar host materials with strong adsorption capacity of polysulfides are designed to limit the
shuttle effect in sulfur cathodes. However, a critical problem is to control diffusion and …

[HTML][HTML] Local effects of ring topology observed in polymer conformation and dynamics by neutron scattering—A review

V Arrighi, JS Higgins - Polymers, 2020 - mdpi.com
The physical properties of polymers depend on a range of both structural and chemical
parameters, and in particular, on molecular topology. Apparently simple changes such as …

Stress relaxation in symmetric ring-linear polymer blends at low ring fractions

D Parisi, J Ahn, T Chang, D Vlassopoulos… - …, 2020 - ACS Publications
We combine linear viscoelastic measurements and modeling in order to explore the
dynamics of blends of the same-molecular-weight ring and linear polymers in the regime of …

DNA as a model for probing polymer entanglements: Circular polymers and non-classical dynamics

K Regan, S Ricketts, RM Robertson-Anderson - Polymers, 2016 - mdpi.com
Double-stranded DNA offers a robust platform for investigating fundamental questions
regarding the dynamics of entangled polymer solutions. The exceptional monodispersity …

Melt structure and dynamics of unentangled polyethylene rings: Rouse theory, atomistic molecular dynamics simulation, and comparison with the linear analogues

G Tsolou, N Stratikis, C Baig, PS Stephanou… - …, 2010 - ACS Publications
Atomistic configurations of model unentangled ring polyethylene (PE) melts ranging in chain
length from C24 up to C400 have been subjected to detailed molecular dynamics (MD) …

Effective Click Construction of Bridged- and Spiro-Multicyclic Polymer Topologies with Tailored Cyclic Prepolymers (kyklo-Telechelics)

N Sugai, H Heguri, K Ohta, Q Meng… - Journal of the …, 2010 - ACS Publications
An alkyne− azide addition, ie, click, reaction in conjunction with an electrostatic self-
assembly and covalent fixation (ESA-CF) process has been demonstrated to effectively …

Threading–unthreading transition of linear-ring polymer blends in extensional flow

A Borger, W Wang, TC O'Connor, T Ge… - ACS Macro …, 2020 - ACS Publications
Adding small amounts of ring polymers to a matrix of their linear counterparts is known to
increase the zero-shear-rate viscosity because of linear-ring threading. Uniaxial extensional …

Nucleation and antinucleation effects of functionalized carbon nanotubes on cyclic and linear poly (ε-caprolactones)

RA Perez, JV Lopez, JN Hoskins, B Zhang… - …, 2014 - ACS Publications
Novel nanocomposites were prepared by blending linear or cyclic poly (ε-caprolactones)
with two types of chemically modified carbon nanotubes (CNTs). The low-polydispersity …

Threading of ring poly (ethylene oxide) molecules by linear chains in the melt

DG Tsalikis, VG Mavrantzas - ACS Macro Letters, 2014 - ACS Publications
We report results from an atomistic molecular dynamics simulation study of ring-linear poly
(ethylene oxide)(PEO) melts followed by a topological reduction to ensembles of primitive …