Superatoms in materials science

EA Doud, A Voevodin, TJ Hochuli… - Nature Reviews …, 2020 - nature.com
Clusters are ensembles of bound atoms intermediate in size between a molecule and a bulk
solid. Some of these clusters form stable units with atomically precise structures that give …

Advances in cluster superatoms for a 3D periodic table of elements

Z Luo, S Lin - Coordination Chemistry Reviews, 2024 - Elsevier
Clusters that mimic elemental atoms in the periodic table are known as superatoms which
open up a new window to design functional materials and catalysts by atomic construction …

Structural order enhances charge carrier transport in self-assembled Au-nanoclusters

F Fetzer, A Maier, M Hodas, O Geladari… - Nature …, 2020 - nature.com
The collective properties of self-assembled nanoparticles with long-range order bear
immense potential for customized electronic materials by design. However, to mitigate the …

Smallest [5, 6] fullerene as building blocks for 2D networks with superior stability and enhanced photocatalytic performance

J Wu, B Peng - Journal of the American Chemical Society, 2024 - ACS Publications
The assembly of molecules to form covalent networks can create varied lattice structures
with physical and chemical properties distinct from those of conventional atomic lattices …

Cocrystallization of atomically precise nanoclusters

X Kang, M Zhu - ACS Materials Letters, 2020 - ACS Publications
Of the great classes of nanocluster crystallization,“cocrystallization” has gained significant
attention due to its elucidation of both intracluster structures and intercluster packing modes …

N4Mg6M (M= Li, Na, K) superalkalis for CO2 activation

C Sikorska, N Gaston - The Journal of Chemical Physics, 2020 - pubs.aip.org
Superatoms have exciting properties, including diverse functionalization, redox activity, and
magnetic ordering, so the resulting cluster-assembled solids hold the promise of high …

[HTML][HTML] Impact of static disorder and dynamic disorder on the thermal conductivity of sodium superoxide (NaO2)

H Ramasubramanian, C Shao… - Journal of Applied …, 2024 - pubs.aip.org
The pyrite phase of sodium superoxide, NaO 2⁠, is studied using equilibrium molecular
dynamics simulations and lattice dynamics calculations to understand the impacts of static …

Shape Matching in Superatom Chemistry and Assembly

J Yang, F Wang, JC Russell, TJ Hochuli… - Journal of the …, 2020 - ACS Publications
Creating structures with superatomic nanoclusters rather than atoms offers the possibility of
new hierarchical solids with collective properties. The variability of chemical compositions …

A superatom-assembled B 8 N 2 monolayer acting as an electronic sponge for high-capacity anode materials for Na/K-ion batteries

K Shen, L Cheng, C Xu - Physical Chemistry Chemical Physics, 2024 - pubs.rsc.org
Rechargeable sodium/potassium-ion batteries (SIBs/PIBs) have emerged as appealing
alternatives for lithium-ion batteries due to their earth-abundance and economic benefits …

[HTML][HTML] Reducing the uncertainty caused by the laser spot radius in frequency-domain thermoreflectance measurements of thermal properties

X Wang, M Jeong, AJH McGaughey… - Review of Scientific …, 2022 - pubs.aip.org
In a frequency-domain thermoreflectance (FDTR) experiment, the phase lag between the
surface temperature response and the applied heat flux is fit with an analytical solution to the …