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Solvent effects in palladium catalysed cross-coupling reactions
Palladium catalysed cross-couplings reactions have been a dominant method in synthetic
chemistry for decades. Despite this, the role of the solvent is often taken for granted and …
chemistry for decades. Despite this, the role of the solvent is often taken for granted and …
N‐heterocyclic carbenes: a new concept in organometallic catalysis
WA Herrmann - Angewandte Chemie International Edition, 2002 - Wiley Online Library
N‐Heterocyclic carbenes have become universal ligands in organometallic and inorganic
coordination chemistry. They not only bind to any transition metal, be it in low or high …
coordination chemistry. They not only bind to any transition metal, be it in low or high …
Heterocyclic carbenes: synthesis and coordination chemistry
FE Hahn, MC Jahnke - Angewandte Chemie International …, 2008 - Wiley Online Library
The chemistry of heterocyclic carbenes has experienced a rapid development over the last
years. In addition to the imidazolin‐2‐ylidenes, a large number of cyclic diaminocarbenes …
years. In addition to the imidazolin‐2‐ylidenes, a large number of cyclic diaminocarbenes …
On the nature of the active species in palladium catalyzed Mizoroki–Heck and Suzuki–Miyaura couplings–homogeneous or heterogeneous catalysis, a critical review
A wide array of forms of palladium has been utilized as precatalysts for Heck and Suzuki
coupling reactions over the last 15 years. Historically, nearly every form of palladium used …
coupling reactions over the last 15 years. Historically, nearly every form of palladium used …
Palladium complexes of N‐heterocyclic carbenes as catalysts for cross‐coupling reactions—A synthetic chemist's perspective
EAB Kantchev, CJ O'Brien… - Angewandte Chemie …, 2007 - Wiley Online Library
Abstract Palladium‐catalyzed C C and C N bond‐forming reactions are among the most
versatile and powerful synthetic methods. For the last 15 years, N‐heterocyclic carbenes …
versatile and powerful synthetic methods. For the last 15 years, N‐heterocyclic carbenes …
Well-defined N-heterocyclic carbenes− palladium (II) precatalysts for cross-coupling reactions
Metal-catalyzed cross-coupling reactions, notably those permitting C− C bond formation,
have witnessed a meteoritic development and are now routinely employed as a powerful …
have witnessed a meteoritic development and are now routinely employed as a powerful …
Pd2(dba)3 as a Precursor of Soluble Metal Complexes and Nanoparticles: Determination of Palladium Active Species for Catalysis and Synthesis
Tris (dibenzylideneacetone) dipalladium (Pd2 (dba) 3) is ubiquitously used as a source of
soluble Pd species for catalysis and as a precursor in the synthesis of more complex Pd …
soluble Pd species for catalysis and as a precursor in the synthesis of more complex Pd …
Functionalized imidazolium salts for task-specific ionic liquids and their applications
S Lee - Chemical Communications, 2006 - pubs.rsc.org
Recent developments in task specifically functionalized imidazolium salts, which can be
used for specific tasks ranging from catalysts recycling, supports for organic synthesis …
used for specific tasks ranging from catalysts recycling, supports for organic synthesis …
The chemistry of functionalised N-heterocyclic carbenes
O Kühl - Chemical Society Reviews, 2007 - pubs.rsc.org
This tutorial review presents the synthesis, chemistry and applications of functionalised N-
heterocyclic carbenes NHC and their transition metal complexes. Functionalised NHC …
heterocyclic carbenes NHC and their transition metal complexes. Functionalised NHC …
Iridium and ruthenium complexes with chelating N-heterocyclic carbenes: efficient catalysts for transfer hydrogenation, β-alkylation of alcohols, and N-alkylation of …
Air-stable Ir and Ru complexes of a chelating pyrimidine-functionalized N-heterocyclic
carbene were synthesized. The complexes were characterized by NMR spectroscopy and …
carbene were synthesized. The complexes were characterized by NMR spectroscopy and …