Review of Fe-based spin crossover metal complexes in multiscale device architectures

N Amin, SM Said, MFM Salleh, AM Afifi, N Ibrahim… - Inorganica Chimica …, 2023 - Elsevier
Metal complexes involving d 4-d 7 first-row transition metals exhibit spin-crossover (SCO)
behaviour between low-spin and high-spin states in response to external stimuli such as …

Unusual metal centres/coordination spheres in spin crossover compounds

J Olguín - Coordination Chemistry Reviews, 2020 - Elsevier
The most widely studied spin crossover (SCO) systems are those involving hexacoordinate
iron (II) complexes immerse in the “magic” N 6 coordination sphere. In this review the …

[HTML][HTML] Thermodynamical aspects of the spin crossover phenomenon

W Nicolazzi, A Bousseksou - Comptes Rendus Chimie, 2018 - Elsevier
Fundamental aspects of spin crossover (SCO) mechanisms are reviewed through
considerations of ligand/crystal field theory, thermodynamics, and modeling of the …

Observation of a Picosecond Light-Induced Spin Transition in Polymeric Nanorods

M Reinhard, K Kunnus, K Ledbetter, E Biasin… - ACS …, 2024 - ACS Publications
Spin transition (ST) materials are attractive for develo** photoswitchable devices, but their
slow material transformations limit device applications. Size reduction could enable faster …

Complete set of elastic moduli of a spin-crossover solid: Spin-state dependence and mechanical actuation

M Mikolasek, MD Manrique-Juarez… - Journal of the …, 2018 - ACS Publications
Molecular spin crossover complexes are promising candidates for mechanical actuation
purposes. The relationships between their crystal structure and mechanical properties …

Thermal bistability of an ultrathin film of iron (II) spin-crossover molecules directly adsorbed on a metal surface

M Kelai, V Repain, A Tauzin, W Li… - The Journal of …, 2021 - ACS Publications
Spin-crossover molecules are very attractive compounds to realize multifunctional spintronic
devices. Understanding their properties when deposited on metals is therefore crucial for …

Dynamical Mechanical Analysis and Micromechanics Simulations of Spin-Crossover@ Polymer Particulate Composites: Toward Soft Actuator Devices

SE Alavi, B Martin, Y Zan, X Yang… - Chemistry of …, 2023 - ACS Publications
We investigated the interplay between the thermomechanical and spin-crossover (SCO)
properties of a series of stimuli-responsive polymer composites consisting of [Fe (NH2trz) 3] …

Voltage-induced bistability of single spin-crossover molecules in a two-dimensional monolayer

Y Tong, M Kelaï, K Bairagi, V Repain… - The journal of …, 2021 - ACS Publications
Bistable spin-crossover molecules are particularly interesting for the development of
innovative electronic and spintronic devices as they present two spin states that can be …

Structural Insights into Hysteretic Spin‐Crossover in a Set of Iron(II)‐2,6‐bis(1H‐Pyrazol‐1‐yl)Pyridine) Complexes

N Suryadevara, A Mizuno, L Spieker… - … A European Journal, 2022 - Wiley Online Library
Bistable spin‐crossover (SCO) complexes that undergo abrupt and hysteretic (ΔT1/2) spin‐
state switching are desirable for molecule‐based switching and memory applications. In this …

[HTML][HTML] Tutorial on the elastic theory of spin crossover materials

AI Popa, L Stoleriu, C Enachescu - Journal of Applied Physics, 2021 - pubs.aip.org
In this paper, we present the ingredients that allow the building-up of the elastic model, one
of the approaches that successfully describes the phenomena observed in complex spin …