Redox processes are at the heart of synthetic methods that rely on either electrochemistry or
photoredox catalysis, but how do electrochemistry and photoredox catalysis compare? Both …

Asymmetric catalysis is a major theme of research in contemporary synthetic organic
chemistry. The discovery of general strategies for highly enantioselective photochemical …

As the breadth of radical chemistry grows, new means to promote and regulate single-
electron redox activities play increasingly important roles in driving modern synthetic …

Enzymes are excellent catalysts that are increasingly being used in industry and academia.
This perspective is primarily aimed at synthetic organic chemists with limited experience …

Controlling the enantioselectivity of hydrogen atom transfer (HAT) reactions has been a long-
standing synthetic challenge. While recent advances on photoenzymatic catalysis have …

Photocatalyzed organic synthesis transformation is a remarkable green synthetic strategy
because of the advantages of operational simplicity, high chemoselectivities, cheap, and …

Flavin-dependent “ene”-reductases can generate stabilized alkyl radicals when irradiated
with visible light; however, they are not known to form unstabilized radicals. Here, we report …

α-Tertiary amines are a common motif in pharmaceutically important molecules but are
challenging to prepare using asymmetric catalysis. Here, we demonstrate engineered flavin …

With the development of new photocatalytic methods over recent decades, the translation of
these chemical reactions to industrial‐production scales using continuous‐flow reactors has …

The trifluoromethyl (− CF3) group represents a highly prevalent functionality in
pharmaceuticals. Over the past few decades, significant advances have been made in the …