The two-faced reactivity of N-allenamides allows regio-and stereo-controlled
functionalization at the α-, β-and γ-positions of the nitrogen atom. The contingency to obtain …

A copper‐mediated coupling reaction between ynamides and diazo‐compounds to produce
N‐allenamides is reported for the first time. This method enables facile and rapid access to …

An efficient electrophilic N‐cyanation of amines with a stable and less‐toxic
cyanobenziodoxole reagent towards the synthesis of cyanamides is disclosed. This …

The convenient preparation of N2-unprotected five-membered cyclic guanidines was
achieved through a cascade [3+ 2] cycloaddition between organo-cyanamides and α …

An intermolecular radical addition, using photoredox catalysis, to allenamides and
allencarbamates is reported. This transformation synthesizes N-acyl-N'-aryl-N, N' …

In this study, we present a novel and environmentally sustainable protocol for the γ-
hydrofunctionalization of N-allenyl compounds using various heteronucleophiles catalyzed …

In the present research, a recyclable catalyst has been prepared via a simple approach
using chitosan as a linear polysaccharide. This paper reports the synthesis of novel copper …

A practical two-step synthesis of N, N′-disubstituted cyanamides consists in the low-
temperature metalation of N-substituted 5 H-tetrazoles that undergo spontaneous …

Lewis acid‐mediated cyanation of phenol derivatives with N‐cyano‐N‐phenyl‐p‐
toluenesulfonamide (NCTS) has been developed. The reaction proceeded efficiently with …

N-Ts cyanamide, which has been widely used in the construction of nitrogen-containing
framework, is one of the efficient and practical multifunctional synthetic precursors in organic …