N-Heterocyclic carbene complexes in C–H activation reactions

Q Zhao, G Meng, SP Nolan, M Szostak - Chemical reviews, 2020‏ - ACS Publications
In this contribution, we provide a comprehensive overview of C–H activation methods
promoted by NHC–transition metal complexes, covering the literature since 2002 (the year …

Palladium-catalyzed transformations of alkyl C–H bonds

J He, M Wasa, KSL Chan, Q Shao, JQ Yu - Chemical Reviews, 2017‏ - ACS Publications
This Review summarizes the advancements in Pd-catalyzed C (sp3)–H activation via
various redox manifolds, including Pd (0)/Pd (II), Pd (II)/Pd (IV), and Pd (II)/Pd (0). While few …

Methane conversion into different hydrocarbons or oxygenates: current status and future perspectives in catalyst development and reactor operation

EV Kondratenko, T Peppel, D Seeburg… - Catalysis Science & …, 2017‏ - pubs.rsc.org
This Perspective highlights recent developments in methane conversion into different
hydrocarbons and oxygenates (methanol, its derivatives, and formaldehyde) with the …

Increasing catalyst efficiency in C− H activation catalysis

T Gensch, MJ James, T Dalton… - Angewandte Chemie …, 2018‏ - Wiley Online Library
C− H activation reactions with high catalyst turnover numbers are still very rare in the
literature and 10 mol% is a common catalyst loading in this field. We offer a representative …

New trends in oxidative functionalization of carbon–hydrogen bonds: A review

GB Shul'pin - Catalysts, 2016‏ - mdpi.com
This review describes new reactions catalyzed by recently discovered types of metal
complexes and catalytic systems (catalyst+ co-catalyst). Works of recent years (mainly 2010 …

Deep oxidation of propane over WO3-promoted Pt/BN catalysts: The critical role of Pt-WO3 interface

WM Liao, XX Fang, BH Cen, J Chen, YR Liu… - Applied Catalysis B …, 2020‏ - Elsevier
The addition of WO 3 in the Pt/BN catalyst significantly promotes the performance for deep
oxidation of propane. A catalyst with a W content of 7 wt.%(1 Pt-7 W/BN) has the highest …

Metal‐Free Photocatalysts for C− H Bond Oxygenation Reactions with Oxygen as the Oxidant

Y Zhang, W Schilling, S Das - ChemSusChem, 2019‏ - Wiley Online Library
Direct and selective oxygenation of C− H bonds to C− O bonds is regarded as an effective
tool to generate high‐value products. However, these reactions are still subject to …

Synthesis of hemilabile cyclic (alkyl)(amino) carbenes (CAACs) and applications in organometallic chemistry

J Chu, D Munz, R Jazzar, M Melaimi… - Journal of the American …, 2016‏ - ACS Publications
A versatile methodology, involving readily available starting materials, allows for the
synthesis of stable hemilabile bidentate cyclic (alkyl)(amino) carbenes (CAACs) featuring …

Light-mediated aerobic oxidation of C (sp 3)–H bonds by a Ce (iv) hexachloride complex

YH Wang, Q Yang, PJ Walsh… - Organic Chemistry …, 2022‏ - pubs.rsc.org
A photochemical C (sp3)–H oxygenation of alkane and arene substrates catalyzed by [NEt4]
2 [CeIVCl6] under mild conditions (1 atm, 25° C) is described. Time-course studies reveal …

Promotional effects of Ag on catalytic combustion of cyclohexane over PdAg/Ti-SBA-15

S Song, Q Liu, J **ong, M Wen, T An - Journal of Catalysis, 2023‏ - Elsevier
Recently, PdM bimetallic nanoparticle-supported catalysts have attracted considerable
attention as superior catalysts for VOC combustion due to the promotional effect rendered by …