[HTML][HTML] Bifunctional ligands in uranyl chemistry: metalloligands and zwitterions

P Thuéry, J Harrowfield - Coordination Chemistry Reviews, 2024 - Elsevier
Structural studies of uranyl ion complexes of metalloligands and zwitterions, ligand classes
with some degree of overlap, constitute a major contribution to more recent developments in …

Resonance‐assisted hydrogen bonding as a driving force in synthesis and a synthon in the design of materials

KT Mahmudov, AJL Pombeiro - Chemistry–A European …, 2016 - Wiley Online Library
Resonance‐assisted hydrogen bonding (RAHB), a concept introduced by Gilli and co‐
workers in 1989, concerns a kind of intramolecular H‐bonding strengthened by a …

4-(Ammoniomethyl) benzoate, a protic zwitterionic bifunctional linker in uranyl ion carboxylate complexes

Y Atoini, J Harrowfield, P Thuéry - CrystEngComm, 2024 - pubs.rsc.org
4-(Aminomethyl) benzoic acid (Hamb) has been found to complex the uranyl ion in its
neutral, zwitterionic form in a series of mixed-ligand complexes synthesized under solvo …

Engaging the terminal: promoting halogen bonding interactions with uranyl oxo atoms

KP Carter, M Kalaj, RG Surbella III… - … A European Journal, 2017 - Wiley Online Library
Engaging the nominally terminal oxo atoms of the linear uranyl (UO22+) cation in non‐
covalent interactions represents both a significant challenge and opportunity within the field …

Multifunctional uranyl hybrid materials: structural diversities as a function of pH, luminescence with potential nitrobenzene sensing, and photoelectric behavior as p …

J Song, X Gao, ZN Wang, CR Li, Q Xu, FY Bai… - Inorganic …, 2015 - ACS Publications
A series of uranyl–organic frameworks (UOFs),{[(UO2) 2 (H2TTHA)(H2O)]· 4, 4′-bipy·
2H2O} n (1),{[(UO2) 3 (TTHA)(H2O) 3]} n (2), and {[(UO2) 5 (TTHA)(HTTHA)(H2O) 3]· H3O} n …

Orbital Engineering Mediated by Cation Conjugation in Luminescent Uranyl‐Organic Hybrid Materials

A Raghavan, CL Cahill - Angewandte Chemie International …, 2024 - Wiley Online Library
A series of compounds of the form [HAr] 2 [UO2X4] is reported here, wherein Ar is
systematically varied between pyridine (1‐X), quinoline (2‐X), acridine (3‐X), 2, 5 …

Harnessing uranyl oxo atoms via halogen bonding interactions in molecular uranyl materials featuring 2, 5-diiodobenzoic acid and N-donor cap** ligands

KP Carter, M Kalaj, CL Cahill - Inorganic Chemistry Frontiers, 2017 - pubs.rsc.org
The syntheses and crystal structures of five new compounds containing the UO22+ cation, 2,
5-diiodobenzoic acid, and a chelating N-donor (2, 2′-bipyridine (bipy)(1), 1, 10 …

Combining coordination and supramolecular chemistry to explore uranyl assembly in the solid state

KP Carter, CL Cahill - Inorganic Chemistry Frontiers, 2015 - pubs.rsc.org
The syntheses and crystal structures of twelve new compounds containing the UO22+
cation, a bromo-substituted benzoic acid linker (m-bromo-, p-bromo, or 3, 5-dibromobenzoic …

Impacts of hydrogen bonding interactions with Np (V/VI) O 2 Cl 4 complexes: vibrational spectroscopy, redox behavior, and computational analysis

MM Pyrch, JL Bjorklund, JM Williams, DL Parr IV… - Dalton …, 2020 - pubs.rsc.org
The neptunyl (Np (V) O2+/Np (VI) O22+) cation is the dominant form of 237Np in acidic
aqueous solutions and the stability of the Np (V) and Np (VI) species is driven by the specific …

Halogen bonded three-dimensional uranyl–organic compounds with unprecedented halogen–halogen interactions and structure diversity upon variation of halogen …

L Mei, C Wang, L Wang, Y Zhao, Z Chai… - Crystal Growth & …, 2015 - ACS Publications
Actinide-based metal–organic materials have drawn much attention due to their intriguing 5f
bonding properties and promising applications in nuclear fuels and other fields. Introduction …