Direct measurement of the local glass transition in self-assembled copolymers with nanometer resolution

D Christie, RA Register, RD Priestley - ACS central science, 2018 - ACS Publications
Nanoscale compositional heterogeneity in block copolymers can impart synergistic property
combinations, such as stiffness and toughness. However, until now, there has been no …

Large-area nanosquare arrays from shear-aligned block copolymer thin films

SY Kim, A Nunns, J Gwyther, RL Davis, I Manners… - Nano …, 2014 - ACS Publications
While block copolymer lithography has been broadly applied as a bottom-up patterning
technique, only a few nanopattern symmetries, such as hexagonally packed dots or parallel …

Stability and Elasticity of Ultrathin Sphere-Patterned Block Copolymer Films

L Qiao, DA Vega, F Schmid - Macromolecules, 2024 - ACS Publications
Sphere-patterned ultrathin block copolymer films are potentially interesting for a variety of
applications in nanotechnology. We use self-consistent field theory to investigate the elastic …

Cylinder Orientation and Shear Alignment in Thin Films of Polystyrene–Poly(n-hexyl methacrylate) Diblock Copolymers

RL Davis, PM Chaikin, RA Register - Macromolecules, 2014 - ACS Publications
Thin films of cylinder-forming polystyrene–poly (n-hexyl methacrylate) diblock copolymers,
PS–PHMA, are attractive as nanolithographic templates, an application which demands …

SAXS signature of the lamellar ordering of ionic domains of perfluorinated sulfonic-acid ionomers by electric and magnetic field-assisted casting

JS da Silva, SGM Carvalho, RP da Silva… - Physical Chemistry …, 2020 - pubs.rsc.org
At present, small angle X-ray scattering (SAXS) studies of perfluorinated sulfonic-acid
ionomers (PFSAs) are unable to fully determine the true shape of their building blocks, as …

Progression of alignment in thin films of cylinder-forming block copolymers upon shearing

RL Davis, BT Michal, PM Chaikin, RA Register - Macromolecules, 2015 - ACS Publications
Application of shear stress at the surface of a block copolymer thin film has been shown to
substantially orient the microdomains in the direction of the applied shear. The present work …

Phase behaviors of sphere-forming triblock copolymers confined in nanopores: a dynamic density functional theory study

QH Hao, B Miao, QG Song, XH Niu, TJ Liu - Polymer, 2014 - Elsevier
We have studied the phase behaviors of sphere-forming triblock copolymers in confined
spaces using the mean-field dynamic density functional theory. The focus is on the …

Mixed-morphology and mixed-orientation block copolymer bilayers

NA García, RL Davis, SY Kim, PM Chaikin… - RSC Advances, 2014 - pubs.rsc.org
Block copolymers have attracted considerable attention due to their ability to self-assemble
into highly regular structures, spanning length scales from several nanometers to over 100 …

[PDF][PDF] Supporting Information Progression of Alignment in Thin Films of Cylinder-Forming Block Copolymers upon Shearing

RL Davis, BT Michal, PM Chaikin, RA Register - pstorage-acs-6854636.s3 …
Bound [K] 21-77 98 0.197 22.3 680 6000 30-86 116 0.245 17.9 1270 106* 34-77 111 0.283
15.3 1480 106* 48-88 136 0.332 13.3 2320 106* 31-108 139 0.207 21.2 1180 106* 60-191 …

Phase separation and surface properties of poly(propyl methacrylate-b-methyl methacrylate) diblock copolymers

D Pospiech, R Choińska, K Eckstein, D Jehnichen… - Polymer Bulletin, 2019 - Springer
The phase separation and surface characteristics of poly (propyl methacrylate-b-methyl
methacrylate)(PPrMA-b-PMMA) diblock copolymers were studied and compared to strongly …