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Direct measurement of the local glass transition in self-assembled copolymers with nanometer resolution
Nanoscale compositional heterogeneity in block copolymers can impart synergistic property
combinations, such as stiffness and toughness. However, until now, there has been no …
combinations, such as stiffness and toughness. However, until now, there has been no …
Large-area nanosquare arrays from shear-aligned block copolymer thin films
While block copolymer lithography has been broadly applied as a bottom-up patterning
technique, only a few nanopattern symmetries, such as hexagonally packed dots or parallel …
technique, only a few nanopattern symmetries, such as hexagonally packed dots or parallel …
Stability and Elasticity of Ultrathin Sphere-Patterned Block Copolymer Films
Sphere-patterned ultrathin block copolymer films are potentially interesting for a variety of
applications in nanotechnology. We use self-consistent field theory to investigate the elastic …
applications in nanotechnology. We use self-consistent field theory to investigate the elastic …
Cylinder Orientation and Shear Alignment in Thin Films of Polystyrene–Poly(n-hexyl methacrylate) Diblock Copolymers
Thin films of cylinder-forming polystyrene–poly (n-hexyl methacrylate) diblock copolymers,
PS–PHMA, are attractive as nanolithographic templates, an application which demands …
PS–PHMA, are attractive as nanolithographic templates, an application which demands …
SAXS signature of the lamellar ordering of ionic domains of perfluorinated sulfonic-acid ionomers by electric and magnetic field-assisted casting
JS da Silva, SGM Carvalho, RP da Silva… - Physical Chemistry …, 2020 - pubs.rsc.org
At present, small angle X-ray scattering (SAXS) studies of perfluorinated sulfonic-acid
ionomers (PFSAs) are unable to fully determine the true shape of their building blocks, as …
ionomers (PFSAs) are unable to fully determine the true shape of their building blocks, as …
Progression of alignment in thin films of cylinder-forming block copolymers upon shearing
Application of shear stress at the surface of a block copolymer thin film has been shown to
substantially orient the microdomains in the direction of the applied shear. The present work …
substantially orient the microdomains in the direction of the applied shear. The present work …
Phase behaviors of sphere-forming triblock copolymers confined in nanopores: a dynamic density functional theory study
QH Hao, B Miao, QG Song, XH Niu, TJ Liu - Polymer, 2014 - Elsevier
We have studied the phase behaviors of sphere-forming triblock copolymers in confined
spaces using the mean-field dynamic density functional theory. The focus is on the …
spaces using the mean-field dynamic density functional theory. The focus is on the …
Mixed-morphology and mixed-orientation block copolymer bilayers
Block copolymers have attracted considerable attention due to their ability to self-assemble
into highly regular structures, spanning length scales from several nanometers to over 100 …
into highly regular structures, spanning length scales from several nanometers to over 100 …
[PDF][PDF] Supporting Information Progression of Alignment in Thin Films of Cylinder-Forming Block Copolymers upon Shearing
Bound [K] 21-77 98 0.197 22.3 680 6000 30-86 116 0.245 17.9 1270 106* 34-77 111 0.283
15.3 1480 106* 48-88 136 0.332 13.3 2320 106* 31-108 139 0.207 21.2 1180 106* 60-191 …
15.3 1480 106* 48-88 136 0.332 13.3 2320 106* 31-108 139 0.207 21.2 1180 106* 60-191 …
Phase separation and surface properties of poly(propyl methacrylate-b-methyl methacrylate) diblock copolymers
D Pospiech, R Choińska, K Eckstein, D Jehnichen… - Polymer Bulletin, 2019 - Springer
The phase separation and surface characteristics of poly (propyl methacrylate-b-methyl
methacrylate)(PPrMA-b-PMMA) diblock copolymers were studied and compared to strongly …
methacrylate)(PPrMA-b-PMMA) diblock copolymers were studied and compared to strongly …