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Ag (I) N-heterocyclic carbene complexes: synthesis, structure, and application
Ofele and Wanzlick first pioneered the metalation of imidazol-2-ylidenes, better known as N-
heterocyclic carbenes (NHCs), from imidazolium salts in 1968. 1, 2 Lappert and co-workers …
heterocyclic carbenes (NHCs), from imidazolium salts in 1968. 1, 2 Lappert and co-workers …
Preparation and application of N-heterocyclic carbene complexes of Ag (I)
The current status (up to 31 July 2006) of Ag (I)–NHCs (NHC= N-heterocyclic carbene) is
presented with various NHC systems ranging from five membered to seven membered rings …
presented with various NHC systems ranging from five membered to seven membered rings …
Remarkable catalytic activity of dinitrogen-bridged dimolybdenum complexes bearing NHC-based PCP-pincer ligands toward nitrogen fixation
Intensive efforts for the transformation of dinitrogen using transition metal–dinitrogen
complexes as catalysts under mild reaction conditions have been made. However, limited …
complexes as catalysts under mild reaction conditions have been made. However, limited …
Metal complexes with 'pincer'-type ligands incorporating N-heterocyclic carbene functionalities
The coordination and organometallic chemistry of linear, rigid, tridentate ligands, which
incorporate at least one N-heterocyclic carbene and other 'classical'donors, is reviewed …
incorporate at least one N-heterocyclic carbene and other 'classical'donors, is reviewed …
Neutral Tridentate PNP Ligands and Their Hybrid Analogues: Versatile Non‐Innocent Scaffolds for Homogeneous Catalysis
Ligands in coordination chemistry and homogeneous catalysis are traditionally “static”
spectators that do not actively participate in the catalytic cycle. However, such classic …
spectators that do not actively participate in the catalytic cycle. However, such classic …
NHC–Ru complexes—Friendly catalytic tools for manifold chemical transformations
N-Heterocyclic carbenes are now commonly encountered in organometallic and inorganic
coordination chemistry. The increasing attention they enjoy is due to their ability to act as …
coordination chemistry. The increasing attention they enjoy is due to their ability to act as …
Ruthenium pincer complexes: Ligand design and complex synthesis
Active transition–metal complexes based on relatively inexpensive metals are considered to
be a desirable method for sustainable human industrial growth. Considering their cost …
be a desirable method for sustainable human industrial growth. Considering their cost …
N-heterocyclic carbenes as bridgehead donors in metal pincer complexes
Rigid terdentate 'pincer'ligands containing a bridgehead N-heterocyclic carbene (NHC)
donor attract considerable interest as spectators in transition metal complexes with broad …
donor attract considerable interest as spectators in transition metal complexes with broad …
CH activation reactions of ruthenium N-heterocyclic carbene complexes: application in a catalytic tandem reaction involving CC bond formation from alcohols
S Burling, BM Paine, D Nama, VS Brown… - Journal of the …, 2007 - ACS Publications
A series of ruthenium hydride N-alkyl heterocyclic carbene complexes has been
investigated as catalysts for a tandem oxidation/Wittig/reduction reaction to give CC bonds …
investigated as catalysts for a tandem oxidation/Wittig/reduction reaction to give CC bonds …
Ruthenium (II) picolyl-NHC complexes: synthesis, characterization, and catalytic activity in amine N-alkylation and transfer hydrogenation reactions
Ruthenium (II) p-cymene complexes with picolyl-functionalized N-heterocyclic carbenes [(η6-
p-cymene) Ru (L)(Cl)][PF6](L= 3-methyl-1-(2-picolyl) imidazol-2-ylidene (1a), 3-isopropyl-1 …
p-cymene) Ru (L)(Cl)][PF6](L= 3-methyl-1-(2-picolyl) imidazol-2-ylidene (1a), 3-isopropyl-1 …