Cobalt has become increasingly attractive in homogeneous catalysis because of its unique
characteristics and outstanding catalytic performance in addition to being cheap and earth …

Transition metal hydrides play a critical role in stoichiometric and catalytic transformations.
Knowledge of free energies for cleaving metal hydride bonds enables the prediction of …

Strategies to achieve spatiotemporal regulation of pre‐existing alkenes via external stimuli
are essential given the ubiquity of feedstock olefins in chemistry and their downstream …

One-pot reactions elaborated around transition metal-catalyzed isomerization of alkenes not
only offer the inherent advantages of atom-, step-and redox-economy but also enable the …

Access to regioselective monofluorinated alkenes concurrently from fluoroalkenylating
building blocks such as gem-difluorocyclopropanes represents a powerful synthetic tool and …

Full control over the selectivity of carbon–carbon double-bond migrations would enable
access to stereochemically defined olefins that are central to the pharmaceutical, food …

Axially chiral styrenes are of great interest since they may serve as a class of novel chiral
ligands in asymmetric synthesis. However, only recently have strategies been developed for …

Small-ring chemistry is a fascinating field in organic chemistry. gem-Difluorinated
cyclopropanes, a unique class of cyclopropanes, have garnered significant interest due to …

Hydroamination facilitated by metal hydride catalysis is an appealing synthetic approach to
access valuable nitrogen-containing compounds from readily available unsaturated …

The isomerization of 1, 1-disubstituted alkenes through 1, 3-hydrogen shift is an atom-
efficient route for synthesizing trisubstituted alkenes, which are important moieties in many …