Chiral metal–organic frameworks

W Gong, Z Chen, J Dong, Y Liu, Y Cui - Chemical Reviews, 2022 - ACS Publications
In the past two decades, metal–organic frameworks (MOFs) or porous coordination polymers
(PCPs) assembled from metal ions or clusters and organic linkers via metal–ligand …

MOF-enabled confinement and related effects for chemical catalyst presentation and utilization

J Liu, TA Goetjen, Q Wang, JG Knapp… - Chemical Society …, 2022 - pubs.rsc.org
A defining characteristic of nearly all catalytically functional MOFs is uniform, molecular-
scale porosity. MOF pores, linkers and nodes that define them, help regulate reactant and …

Generating catalytic sites in UiO-66 through defect engineering

X Feng, HS Jena, C Krishnaraj, K Leus… - … Applied Materials & …, 2021 - ACS Publications
UiO-66 is regarded as an epitome of metal–organic frameworks (MOFs) because of its
stability. Defect engineering has been used as a toolbox to alter the performance of MOFs …

Metal–organic frameworks as catalytic selectivity regulators for organic transformations

J Guo, Y Qin, Y Zhu, X Zhang, C Long… - Chemical Society …, 2021 - pubs.rsc.org
Selective organic transformations using metal–organic frameworks (MOFs) and MOF-based
heterogeneous catalysts have been an intriguing but challenging research topic in both the …

Electronic structure modeling of metal–organic frameworks

JL Mancuso, AM Mroz, KN Le, CH Hendon - Chemical reviews, 2020 - ACS Publications
Owing to their molecular building blocks, yet highly crystalline nature, metal–organic
frameworks (MOFs) sit at the interface between molecule and material. Their diverse …

Asymmetric catalysis using metal-organic frameworks

DN Dybtsev, KP Bryliakov - Coordination Chemistry Reviews, 2021 - Elsevier
To date, porous coordination polymers (metal–organic frameworks, MOFs) have been
extensively studied in multiple applications, including the use of homohiral or chirally …

Homochiral metal–organic frameworks for enantioseparation

J Liu, S Mukherjee, F Wang, RA Fischer… - Chemical Society …, 2021 - pubs.rsc.org
Obtaining homochiral compounds is of high importance to human health and environmental
sustainability. Currently, enantioseparation is one of the most effective approaches to obtain …

Defect-engineered metal–organic frameworks (MOF-808) towards the improved adsorptive removal of organic dyes and chromium (vi) species from water

KD Nguyen, NT Vo, KTM Le, KV Ho… - New Journal of …, 2023 - pubs.rsc.org
In this work, two defective zirconium-based metal–organic frameworks (Zr-MOFs), MOF-808-
OH and MOF-808-NH2, were synthesized by partially replacing the 1, 3, 5 …

Amino acid‐functionalized metal‐organic frameworks for asymmetric base–metal catalysis

R Newar, N Akhtar, N Antil, A Kumar… - Angewandte Chemie …, 2021 - Wiley Online Library
We report a strategy to develop heterogeneous single‐site enantioselective catalysts based
on naturally occurring amino acids and earth‐abundant metals for eco‐friendly asymmetric …

Chiral iron (II)-catalysts within valinol-grafted metal–organic frameworks for enantioselective reduction of ketones

N Antil, N Akhtar, R Newar, W Begum, A Kumar… - ACS …, 2021 - ACS Publications
The development of highly efficient and enantioselective heterogeneous catalysts based on
earth-abundant elements and inexpensive chiral ligands is essential for environment …