Reversible-deactivation radical polymerization (Controlled/living radical polymerization): From discovery to materials design and applications

N Corrigan, K Jung, G Moad, CJ Hawker… - Progress in Polymer …, 2020 - Elsevier
Reversible-deactivation radical polymerization (RDRP) processes, such as atom transfer
radical polymerization (ATRP), reversible addition-fragmentation chain transfer (RAFT) …

Precision polymer synthesis by controlled radical polymerization: Fusing the progress from polymer chemistry and reaction engineering

YN Zhou, JJ Li, TT Wang, YY Wu, ZH Luo - Progress in Polymer Science, 2022 - Elsevier
During the first 100 years of polymer science, controlled radical polymerization (also
recommended as reversible deactivation radical polymerization) is undoubtedly a …

Bulk depolymerization of poly (methyl methacrylate) via chain-end initiation for catalyst-free reversion to monomer

JB Young, RW Hughes, AM Tamura, LS Bailey… - Chem, 2023 - cell.com
We present the bulk depolymerization of poly (methyl methacrylate)(PMMA) at significantly
lower temperatures than previously reported methods through the incorporation of …

50th Anniversary Perspective: RAFT PolymerizationA User Guide

S Perrier - Macromolecules, 2017 - ACS Publications
This Perspective summarizes the features and limitations of reversible addition–
fragmentation chain transfer (RAFT) polymerization, highlighting its strengths and …

Surface-initiated controlled radical polymerization: state-of-the-art, opportunities, and challenges in surface and interface engineering with polymer brushes

JO Zoppe, NC Ataman, P Mocny, J Wang… - Chemical …, 2017 - ACS Publications
The generation of polymer brushes by surface-initiated controlled radical polymerization (SI-
CRP) techniques has become a powerful approach to tailor the chemical and physical …

Rare earth metal–organic frameworks (RE-MOFs): Synthesis, properties, and biomedical applications

SA Younis, N Bhardwaj, SK Bhardwaj, KH Kim… - Coordination Chemistry …, 2021 - Elsevier
Rare earth metal–organic frameworks (RE-MOFs) have drawn a good deal of research
interest due to their unique properties (eg, luminescence, magneticity, and intrinsic porosity) …

Thermoresponsive polymer nanocarriers for biomedical applications

A Bordat, T Boissenot, J Nicolas, N Tsapis - Advanced drug delivery …, 2019 - Elsevier
Polymer nanocarriers allow drug encapsulation leading to fragile molecule protection from
early degradation/metabolization, increased solubility of poorly soluble drugs and improved …

Photoinduced electron transfer reactions for macromolecular syntheses

S Dadashi-Silab, S Doran, Y Yagci - Chemical reviews, 2016 - ACS Publications
Photochemical reactions, particularly those involving photoinduced electron transfer
processes, establish a substantial contribution to the modern synthetic chemistry, and the …

Up in the air: oxygen tolerance in controlled/living radical polymerisation

J Yeow, R Chapman, AJ Gormley… - Chemical Society Reviews, 2018 - pubs.rsc.org
The requirement for deoxygenation in controlled/living radical polymerisation (CLRP) places
significant limitations on its widespread implementation by necessitating the use of large …

A versatile 3D and 4D printing system through photocontrolled RAFT polymerization

Z Zhang, N Corrigan, A Bagheri, J **… - Angewandte Chemie …, 2019 - Wiley Online Library
Reversible addition‐fragmentation chain‐transfer (RAFT) polymerization is a valuable tool
for synthesizing macromolecules with controlled topologies and diverse chemical …