We present an update and revision to our 2010 review on the topic of proton-coupled
electron transfer (PCET) reagent thermochemistry. Over the past decade, the data and …

Abstract NAD (P) H-dependent oxidoreductases catalyze the reduction or oxidation of a
substrate coupled to the oxidation or reduction, respectively, of a nicotinamide adenine …

Microbial degradation is an important option for combating antibiotic pollution. Arthrobacter
nicotianae OTC-16 was isolated as a novel tetracycline-degrading bacterium, which could …

When challenged by a difficult reduction reaction, a chemist should always also consider
biocatalysis in synthesis planning. The inherent selectivity of enzymes has been known for …

Most nitroaromatic compounds are toxic and mutagenic for living organisms, but some
microorganisms have developed oxidative or reductive pathways to degrade or transform …

Within the last few years, knowledge about vitamins has increased dramatically. This new
edition of a bestseller presents comprehensive summaries that analyze the chemical …

The old yellow enzyme (OYE) family is a large group of flavin‐dependent redox biocatalysts
with major applications in the industrial reduction of activated alkenes. These enzymes have …

The asymmetric bioreduction of alkenes bearing an electron-withdrawing group using flavin-
dependent enzymes from the 'old yellow enzyme'family at the expense of NAD (P) H yields …

At some point during biosynthesis of the antimalarial artemisinin in glandular trichomes of
Artemisia annua, the Δ11 (13) double bond originating in amorpha-4, 11-diene is reduced …

Flavin has long been known to function as a single electron reductant in biological settings,
but this reactivity has rarely been observed with flavoproteins used in organic synthesis …