A novel phytosterol isolated from Datura inoxia, RinoxiaB is a potential cure colon cancer agent by targeting BAX/Bcl2 pathway
Plant sterols have been widely used as chemotherapeutic agents for colorectal cancer for
years together. In this study, a novel phytosterol was isolated and characterized from the leaf …
years together. In this study, a novel phytosterol was isolated and characterized from the leaf …
New routes to a series of σ‐borane/borate complexes of Molybdenum and Ruthenium
A series of agostic σ‐borane/borate complexes have been synthesized and structurally
characterized from simple borane adducts. A room‐temperature reaction of [Cp* Mo (CO) …
characterized from simple borane adducts. A room‐temperature reaction of [Cp* Mo (CO) …
Hexagonal Bipyramidal [Ta2B6]−/0 Clusters: B6 Rings as Structural Motifs
It has been a long‐sought goal in cluster science to discover stable atomic clusters as
building blocks for cluster‐assembled nanomaterials, as exemplified by the fullerenes and …
building blocks for cluster‐assembled nanomaterials, as exemplified by the fullerenes and …
First‐Row Transition‐Metal–Diborane and–Borylene Complexes
A combined experimental and quantum chemical study of Group 7 borane, trimetallic triply
bridged borylene and boride complexes has been undertaken. Treatment of [{Cp* CoCl} …
bridged borylene and boride complexes has been undertaken. Treatment of [{Cp* CoCl} …
Trithia-diborinane and Bis(bridging-boryl) Complexes of Ruthenium Derived from a [BH3(SCHS)]− Ion
The field of diborinane is sparsely explored area, and not many compounds are structurally
characterized. The room-temperature reaction of [{Cp* RuCl (μ-Cl)} 2](Cp*= η5-C5Me5) with …
characterized. The room-temperature reaction of [{Cp* RuCl (μ-Cl)} 2](Cp*= η5-C5Me5) with …
η4‐HBCC‐σ,π‐Borataallyl Complexes of Ruthenium Comprising an Agostic Interaction
Abstract Thermolysis of [Cp* Ru (PPh2 (CH2) PPh2) BH2 (L2)] 1 (Cp*= η5‐C5Me5; L=
C7H4NS2), with terminal alkynes led to the formation of η4‐σ, π‐borataallyl complexes [Cp …
C7H4NS2), with terminal alkynes led to the formation of η4‐σ, π‐borataallyl complexes [Cp …
Stabilization of Ethane‐Like Dianionic Diborane(6) in Monometallic Titanium Complexes and its Subsequent B(sp3)−B(sp3) Bond Cleavage
Abstract Treatment of [Cp* TiCl3] with [LiBH4⋅ THF] followed by thermolysis with [Ph2E2](E=
S or Se) resulted in the formation of classical diborane (6) complexes,[(Cp* Ti)(η4 …
S or Se) resulted in the formation of classical diborane (6) complexes,[(Cp* Ti)(η4 …
Chalcogen stabilized trimetallic clusters: synthesis, structures, and bonding of [(Cp* M) 3 (E) 6+ m (BH) n](M= Nb or Ta; E= S or Se; m= 0 or 1 or 2; n= 0 or 1)
In an effort to isolate the chalcogen-rich niobium analogue of [(Cp* Ta) 3 (μ-S) 3 (μ3-S) 3BH],
the room temperature reaction of [Cp* NbCl4](Cp*= η5-C5Me5) with Li [BH2S3] was carried …
the room temperature reaction of [Cp* NbCl4](Cp*= η5-C5Me5) with Li [BH2S3] was carried …
Hydroboration of alkynes with zwitterionic ruthenium–borate complexes: novel vinylborane complexes
Building upon previous studies on the synthesis of bis (sigma) borate and agostic
complexes of ruthenium, the chemistry of nido‐[(Cp* Ru) 2B3H9](1) with other ligand …
complexes of ruthenium, the chemistry of nido‐[(Cp* Ru) 2B3H9](1) with other ligand …
B–H Functionalization of Hydrogen-Rich [(Cp*V)2(B2H6)2]: Synthesis and Structures of [(Cp*V)2(B2X2)2H8] (X = Cl, SePh; Cp* = η5-C5Me5)
A Haridas, S Kar, B Raghavendra, T Roisnel… - …, 2019 - ACS Publications
We have recently reported the perchlorinated diniobaborane species [(Cp* Nb) 2 (B2H4Cl2)
2] from [(Cp* Nb) 2 (B2H6) 2] using CCl4 as a chlorinating agent. In an attempt to isolate the …
2] from [(Cp* Nb) 2 (B2H6) 2] using CCl4 as a chlorinating agent. In an attempt to isolate the …