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Recent advances in metal-catalyzed asymmetric 1, 4-conjugate addition (ACA) of nonorganometallic nucleophiles
The metal-catalyzed asymmetric conjugate addition (ACA) reaction has emerged as a
general and powerful approach for the construction of optically active compounds and is …
general and powerful approach for the construction of optically active compounds and is …
Catalytic asymmetric synthesis of butenolides and butyrolactones
γ-Butenolides, γ-butyrolactones, and derivatives, especially in enantiomerically pure form,
constitute the structural core of numerous natural products which display an impressive …
constitute the structural core of numerous natural products which display an impressive …
New developments of the principle of vinylogy as applied to π-extended enolate-type donor systems
The principle of vinylogy states that the electronic effects of a functional group in a molecule
are possibly transmitted to a distal position through interposed conjugated multiple bonds …
are possibly transmitted to a distal position through interposed conjugated multiple bonds …
Enantioselective synthesis of spirocyclohexadienones by NHC‐catalyzed formal [3+ 3] annulation reaction of enals
The enantioselective synthesis of pyrazolone‐fused spirocyclohexadienones was
demonstrated by the reaction of α, β‐unsaturated aldehydes with α‐arylidene pyrazolinones …
demonstrated by the reaction of α, β‐unsaturated aldehydes with α‐arylidene pyrazolinones …
Regio‐and Stereoselective Cascade of β, γ‐Unsaturated Ketones by Dipeptided Phosphonium Salt Catalysis: Stereospecific Construction of Dihydrofuro‐Fused [2, 3 …
H Zhang, J He, Y Chen, C Zhuang… - Angewandte Chemie …, 2021 - Wiley Online Library
Chiral (dihydro) furo‐fused heterocycles are significant structural motifs in numerous natural
products, functional materials and pharmaceuticals. Therefore, develo** efficient methods …
products, functional materials and pharmaceuticals. Therefore, develo** efficient methods …
The chemistry and biology of guanidine natural products
Covering: 2012 to 2014. Previous review: Nat. Prod. Rep., 2012, 29, 1382 The present
review discusses the isolation, structure determination, synthesis, biosynthesis and …
review discusses the isolation, structure determination, synthesis, biosynthesis and …
Rationally designed multifunctional supramolecular iminium catalysis: direct vinylogous Michael addition of unmodified linear dienol substrates
Y Gu, Y Wang, TY Yu, YM Liang, PF Xu - Angewandte Chemie, 2014 - Wiley Online Library
The development of a direct vinylogous Michael addition of linear nucleophilic substrates is
a long‐standing challenge because of the poor reactivity and the considerable difficulty in …
a long‐standing challenge because of the poor reactivity and the considerable difficulty in …
Site-selective, photocatalytic vinylogous amidation of enones
Despite the broad interest in organic compounds possessing a γ-aminocarbonyl motif,
limited strategies for their synthesis have been reported. Herein, we describe a mild and …
limited strategies for their synthesis have been reported. Herein, we describe a mild and …
Asymmetric Catalytic Vinylogous Addition Reactions Initiated by Meinwald Rearrangement of Vinyl Epoxides
J Xu, Y Song, J He, S Dong, L Lin… - Angewandte Chemie, 2021 - Wiley Online Library
The first catalytic asymmetric multiple vinylogous addition reactions initiated by Meinwald
rearrangement of vinyl epoxides were realized by employing chiral N, N′‐dioxide/ScIII …
rearrangement of vinyl epoxides were realized by employing chiral N, N′‐dioxide/ScIII …
Organocatalytic asymmetric vinylogous Michael reactions
Y Yin, Z Jiang - ChemCatChem, 2017 - Wiley Online Library
Since RC Fuson formulated the principle of vinylogy, this platform has been extensively
developed through combining diverse predominant chemical transformations. Among them …
developed through combining diverse predominant chemical transformations. Among them …