Progress in metallo-supramolecular chemistry creates potential to synthesize functional
nano systems and intelligent materials of increasing complexity. In the past four decades …

The flexibility of biomolecules enables them to adapt and transform as a result of signals
received from the external environment, expressing different functions in different contexts …

Self-assembled hosts, inspired by biological receptors and catalysts, show application
potential in sustainable synthesis, energy conversion and medicine. Implementing multiple …

A heteroleptic [Pd2L2L'2] 4+ coordination cage containing a photoswitchable azobenzene-
derived ligand catalyzes the Michael addition reaction between methyl vinyl ketone and …

Heteroleptic coordination cages, nonstatistically assembled from a set of matching ligands,
can be obtained by mixing individual components or via cage-to-cage transformations from …

Conspectus Porous nanostructures and materials based on metal-mediated self-assembly
have developed into a vibrantly studied subdiscipline of supramolecular chemistry during …

Multi-component hierarchically porous materials are an emerging class of materials with
tailored compositions, tunable distribution and sophisticated applications. An increasing …

Supramolecular nanoreactors featuring multiple catalytically active sites are of great
importance, especially for asymmetric catalysis, and are yet challenging to construct. Here …

It is difficult to assemble multi-component metallo-supramolecular architectures in a non-
statistical fashion, which limits their development toward functional materials. Herein, we …

Multicomponent metallo‐supramolecular assembly allows the rational combination of
different building blocks. Discrete multifunctional hosts with an accessible cavity can be …