Advances in the study of supercooled water

P Gallo, J Bachler, LE Bove, R Böhmer… - The European Physical …, 2021 - Springer
In this review, we report recent progress in the field of supercooled water. Due to its
uniqueness, water presents numerous anomalies with respect to most simple liquids …

Second critical point in two realistic models of water

PG Debenedetti, F Sciortino, GH Zerze - Science, 2020 - science.org
The hypothesis that water has a second critical point at deeply supercooled conditions was
formulated to provide a thermodynamically consistent interpretation of numerous …

[HTML][HTML] Studying rare events using forward-flux sampling: Recent breakthroughs and future outlook

S Hussain, A Haji-Akbari - The Journal of Chemical Physics, 2020 - pubs.aip.org
Rare events are processes that occur upon the emergence of unlikely fluctuations. Unlike
what their name suggests, rare events are fairly ubiquitous in nature, as the occurrence of …

Signatures of a liquid–liquid transition in an ab initio deep neural network model for water

TE Gartner III, L Zhang, PM Piaggi, R Car… - Proceedings of the …, 2020 - pnas.org
The possible existence of a metastable liquid–liquid transition (LLT) and a corresponding
liquid–liquid critical point (LLCP) in supercooled liquid water remains a topic of much …

Topological nature of the liquid–liquid phase transition in tetrahedral liquids

A Neophytou, D Chakrabarti, F Sciortino - Nature Physics, 2022 - nature.com
The first-order phase transition between two tetrahedral networks of different density—
introduced as a hypothesis to account for the anomalous behaviour of certain …

[HTML][HTML] Liquid–liquid transition and polyamorphism

H Tanaka - The Journal of Chemical Physics, 2020 - pubs.aip.org
Two or more liquid states may exist even for single-component substances, which is known
as liquid polymorphism, and the transition between them is called liquid–liquid transition …

The anomalies and criticality of liquid water

R Shi, H Tanaka - Proceedings of the National Academy of Sciences, 2020 - pnas.org
The origin of water's anomalies has been a matter of long-standing debate. A two-state
model, dating back to Röntgen, relies on the dynamical coexistence of two types of local …

Ice is born in low-mobility regions of supercooled liquid water

M Fitzner, GC Sosso, SJ Cox, A Michaelides - Proceedings of the National …, 2019 - pnas.org
When an ice crystal is born from liquid water, two key changes occur:(i) The molecules order
and (ii) the mobility of the molecules drops as they adopt their lattice positions. Most …

Evidence of ferroelectric features in low-density supercooled water from ab initio deep neural-network simulations

C Malosso, N Manko, MG Izzo, S Baroni… - Proceedings of the …, 2024 - pnas.org
Over the last decade, an increasing body of evidence has emerged, supporting the
existence of a metastable liquid–liquid critical point in supercooled water whereby two …

Deciphering density fluctuations in the hydration water of Brownian nanoparticles via upconversion thermometry

FE Maturi, RS Raposo Filho, CDS Brites… - The Journal of …, 2024 - ACS Publications
We investigate the intricate relationship among temperature, pH, and Brownian velocity in a
range of differently sized upconversion nanoparticles (UCNPs) dispersed in water. These …