Metalated covalent organic frameworks: from synthetic strategies to diverse applications

Q Guan, LL Zhou, YB Dong - Chemical Society Reviews, 2022 - pubs.rsc.org
Covalent organic frameworks (COFs) are a class of organic crystalline porous materials
discovered in the early 21st century that have become an attractive class of emerging …

Construction of covalent organic frameworks via multicomponent reactions

Q Guan, LL Zhou, YB Dong - Journal of the American Chemical …, 2023 - ACS Publications
Multicomponent reactions (MCRs) combine at least three reactants to afford the desired
product in a highly atom-economic way and are therefore viewed as efficient one-pot …

Linking oxidative and reductive clusters to prepare crystalline porous catalysts for photocatalytic CO2 reduction with H2O

J Zhou, J Li, L Kan, L Zhang, Q Huang, Y Yan… - Nature …, 2022 - nature.com
Mimicking natural photosynthesis to convert CO2 with H2O into value-added fuels achieving
overall reaction is a promising way to reduce the atmospheric CO2 level. Casting the …

2D covalent organic frameworks: from synthetic strategies to advanced optical‐electrical‐magnetic functionalities

C Wang, Z Zhang, Y Zhu, C Yang, J Wu… - Advanced …, 2022 - Wiley Online Library
Covalent organic frameworks (COFs), an emerging class of organic crystalline polymers with
highly oriented structures and permanent porosity, can adopt 2D or 3D architectures …

Organic molecular sieve membranes for chemical separations

H Wang, M Wang, X Liang, J Yuan, H Yang… - Chemical Society …, 2021 - pubs.rsc.org
Molecular separations that enable selective transport of target molecules from gas and liquid
molecular mixtures, such as CO2 capture, olefin/paraffin separations, and organic solvent …

Large‐area free‐standing metalloporphyrin‐based covalent organic framework films by liquid‐air interfacial polymerization for oxygen electrocatalysis

J Tang, Z Liang, H Qin, X Liu, B Zhai, Z Su… - Angewandte …, 2023 - Wiley Online Library
Synthesizing large‐area free‐standing covalent organic framework (COF) films is of vital
importance for their applications but is still a big challenge. Herein, we reported the …

Recent progress on phase engineering of nanomaterials

Q Yun, Y Ge, Z Shi, J Liu, X Wang, A Zhang… - Chemical …, 2023 - ACS Publications
As a key structural parameter, phase depicts the arrangement of atoms in materials.
Normally, a nanomaterial exists in its thermodynamically stable crystal phase. With the …

One‐Dimensional Covalent Organic Frameworks for the 2e Oxygen Reduction Reaction

S An, X Li, S Shang, T Xu, S Yang… - Angewandte Chemie …, 2023 - Wiley Online Library
Two‐dimensional covalent organic frameworks (2D COFs) are often employed for
electrocatalytic systems because of their structural diversity. However, the efficiency of atom …

Observation of interpenetrated topology isomerism for covalent organic frameworks with atom-resolution single crystal structures

B Yu, W Li, X Wang, JH Li, RB Lin… - Journal of the …, 2023 - ACS Publications
Rational control and understanding of isomerism are of significance but still remain a great
challenge in reticular frameworks, in particular, for covalent organic frameworks (COFs) due …

Photocatalytic CO2 reduction to syngas using metallosalen covalent organic frameworks

W Zhou, X Wang, W Zhao, N Lu, D Cong, Z Li… - Nature …, 2023 - nature.com
Metallosalen-covalent organic frameworks have recently gained attention in photocatalysis.
However, their use in CO2 photoreduction is yet to be reported. Moreover, facile preparation …