Molecular-level understanding of metal ion retention in clay-rich materials

X Liu, C Tournassat, S Grangeon… - Nature Reviews Earth & …, 2022 - nature.com
Clay minerals retain or adsorb metal ions in the Earth's critical zone. Rocks, sediments and
soils rich in clay minerals can concentrate rare earth elements (REEs) in ion adsorption-type …

Review of application of molecular dynamic simulations in geological high-level radioactive waste disposal

Z Ma, RP Gamage, T Rathnaweera, L Kong - Applied Clay Science, 2019 - Elsevier
This review summarizes current progress in molecular dynamic (MD) simulation in the
context of geological high-level radioactive waste disposal (HLRW). Geological HLRW …

Swelling properties of montmorillonite and beidellite clay minerals from molecular simulation: comparison of temperature, interlayer cation, and charge location effects

SL Teich-McGoldrick, JA Greathouse… - The Journal of …, 2015 - ACS Publications
The swelling properties of smectite clay minerals are relevant to many engineering
applications including environmental remediation, repository design for nuclear waste …

Selective adsorption of cesium from an aqueous solution by a montmorillonite-prussian blue hybrid

HA Alamudy, K Cho - Chemical Engineering Journal, 2018 - Elsevier
Cesium generated from nuclear power plants is the primary source of problems for human
health and environment due to its gamma radiation and high fission yield. Among the …

Multicomponent diffusion of a suite of tracers (HTO, Cl, Br, I, Na, Sr, Cs) in a single sample of Opalinus Clay

CAJ Appelo, LR Van Loon, P Wersin - Geochimica et Cosmochimica Acta, 2010 - Elsevier
Diffusion experiments with HTO, 36Cl−, Br−, I−, 22Na+, 85Sr2+ and 134Cs+ at trace
concentrations in a single sample of Opalinus Clay are modeled with PHREEQC's …

Structural arrangements of isomorphic substitutions in smectites: Molecular simulation of the swelling properties, interlayer structure, and dynamics of hydrated Cs …

BF Ngouana W, AG Kalinichev - The Journal of Physical Chemistry …, 2014 - ACS Publications
Three new structural models of montmorillonite with differently distributed Al/Si and Mg/Al
substitutions in the tetrahedral and octahedral clay layers are systematically developed and …

Radiocesium interaction with clay minerals: Theory and simulation advances Post–Fukushima

M Okumura, S Kerisit, IC Bourg, LN Lammers… - Journal of …, 2018 - Elsevier
Insights at the microscopic level of the process of radiocesium adsorption and interaction
with clay mineral particles have improved substantially over the past several years, triggered …

Hydration and Mobility of Interlayer Ions of (Nax, Cay)-Montmorillonite: A Molecular Dynamics Study

L Zhang, X Lu, X Liu, J Zhou… - The Journal of Physical …, 2014 - ACS Publications
In most of natural montmorillonites, Na+ and Ca2+ ions commonly coexist in the interlayer
space as compensation ions. Molecular dynamics simulations have been performed to …

Revealing transition states during the hydration of clay minerals

TA Ho, LJ Criscenti, JA Greathouse - The journal of physical …, 2019 - ACS Publications
A molecular-scale understanding of the transition between hydration states in clay minerals
remains a challenging problem because of the very fast stepwise swelling process observed …

Nanoscale elastic properties of montmorillonite upon water adsorption

D Ebrahimi, RJM Pellenq, AJ Whittle - Langmuir, 2012 - ACS Publications
Smectites are an important group of clay minerals that experience swelling upon water
adsorption. This paper uses molecular dynamics with the CLAYFF force field to simulate …