Novel approach to analyze metastable zone width determined by the polythermal method: physical interpretation of various parameters

K Sangwal - Crystal Growth and Design, 2009 - ACS Publications
Experimental data on the maximum supercooling Δ T max, a measure of metastable zone
width, for solutions saturated at a temperature T 0, as a function of cooling rate R are …

A novel self‐consistent Nývlt‐like equation for metastable zone width determined by the polythermal method

K Sangwal - Crystal Research and Technology: Journal of …, 2009 - Wiley Online Library
Using a power‐law relation between three‐dimensional nucleation rate J and
dimensionless supersaturation ratio S, and the theory of regular solutions to describe the …

The effect of cation: anion ratio in solution on the mechanism of barite growth at constant supersaturation: Role of the desolvation process on the growth kinetics

M Kowacz, CV Putnis, A Putnis - Geochimica et cosmochimica acta, 2007 - Elsevier
The mechanism of barite growth has been investigated in a fluid cell of an Atomic Force
Microscope by passing solutions of constant supersaturation (Ω) but variable ion activity …

[HTML][HTML] Modifying supersaturation rate with membrane area to volume ratio: Scaling reduction and improved crystal growth control in membrane distillation …

A Ouda, YB Fernández, E McAdam - Journal of Membrane Science, 2023 - Elsevier
This study provides detailed characterisation of nucleation kinetics, induction time and
supersaturation to understand scaling and crystal growth in membrane distillation …

Nucleation behavior of eszopiclone-butyl acetate solutions from metastable zone widths

S Xu, J Wang, K Zhang, S Wu, S Liu, K Li, B Yu… - Chemical Engineering …, 2016 - Elsevier
Experimental data on the critical supercooling∆ T max, a measure of metastable zone width
(MSZWs), as a function of saturated temperature T 0 and cooling rate R were analyzed to …

Nucleation behavior of isosorbide 5-mononitrate revealed from metastable zone widths by combining nucleation theory model and molecular simulation

Y Cao, T Yao, G Zhang, Z Zhou, L Zhai, S Wu - Journal of Molecular Liquids, 2022 - Elsevier
Abstract Isosorbide 5-mononitrate (5-ISMN) crystal has a needle-like morphology with an
aspect ratio greater than 20, which brings great inconvenience to post-processing and …

Insights into solvent-dependent nucleation behavior of benzoic acid from metastable zone widths

S Xu, H Zhang, B Qiao, Y Wang - Journal of Molecular Liquids, 2021 - Elsevier
Currently, how the solvents and temperature affect the solution species and rate-determining
step in the nucleation process, thus altering the nucleation behavior remains elusive. In this …

Insights into the Role of Solvents in Nucleation Kinetics of Glutaric Acid from Metastable Zone Widths

S Xu, Y Bu, S Jiang, P Yang… - Industrial & Engineering …, 2021 - ACS Publications
In this paper, the nucleation behavior of glutaric acid (GA) in solvents with different hydrogen-
bond donating (HBD) capabilities was studied using a metastable zone width (MSZW) …

Nucleation kinetics-based solvent selection for the liquid antisolvent crystallization of a lipophilic intermediate

S Nandi, L Padrela, L Tajber, A Collas - Journal of Molecular Liquids, 2023 - Elsevier
The fundamental understanding of solubility and nucleation kinetics are two primary pillars
for liquid antisolvent crystallization (LASC) process development. In our present work, the …

[HTML][HTML] Nucleation kinetics from metastable zone widths for sonocrystallization of l-phenylalanine

TH Mastan, M Lenka, D Sarkar - Ultrasonics Sonochemistry, 2017 - Elsevier
This study investigates the effect of ultrasound on metastable zone width (MSZW) during
crystallization of l-phenylalanine from aqueous solution. The solubility of l-phenylalanine in …