Strategies to quench quantum tunneling of magnetization in lanthanide single molecule magnets
Enhancing blocking temperature (TB) is one of the holy grails in Single Molecule Magnets
(SMMs), as any future potential application in this class of molecules is directly correlated to …
(SMMs), as any future potential application in this class of molecules is directly correlated to …
[HTML][HTML] Electronic structure and magnetic anisotropy design of functional metal complexes
Chemical guidelines to target a well-defined electronic structure and magnetic anisotropy
are of primary importance in physics, chemistry and biology. Our literature overview …
are of primary importance in physics, chemistry and biology. Our literature overview …
High-temperature magnetic blocking and magneto-structural correlations in a series of dysprosium (III) metallocenium single-molecule magnets
KR McClain, CA Gould, K Chakarawet, SJ Teat… - Chemical …, 2018 - pubs.rsc.org
A series of dysprosium (III) metallocenium salts,[Dy (CpiPr4R) 2][B (C6F5) 4](R= H (1), Me
(2), Et (3), iPr (4)), was synthesized by reaction of DyI3 with the corresponding known …
(2), Et (3), iPr (4)), was synthesized by reaction of DyI3 with the corresponding known …
A Complete Ab Initio View of Orbach and Raman Spin–Lattice Relaxation in a Dysprosium Coordination Compound
The unique electronic and magnetic properties of lanthanide molecular complexes place
them at the forefront of the race toward high-temperature single-molecule magnets and …
them at the forefront of the race toward high-temperature single-molecule magnets and …
Synthesis and magnetism of neutral, linear metallocene complexes of terbium (II) and dysprosium (II)
The divalent metallocene complexes Ln (CpiPr5) 2 (Ln= Tb, Dy) were synthesized through
the KC8 reduction of Ln (CpiPr5) 2I intermediates and represent the first examples of …
the KC8 reduction of Ln (CpiPr5) 2I intermediates and represent the first examples of …
High performance single-molecule magnets, Orbach or Raman relaxation suppression?
The current figure of merit to evaluate Single Molecule Magnet (SMM) performance is the
blocking temperature (TB). The best SMMs show TB values close to liquid nitrogen boiling …
blocking temperature (TB). The best SMMs show TB values close to liquid nitrogen boiling …
Magnetic axiality: design principles from molecules to materials
Recently, the field of molecular magnets has experienced a remarkable result: magnetic
remanence above liquid nitrogen temperatures (> 77 K); this represents the first example of …
remanence above liquid nitrogen temperatures (> 77 K); this represents the first example of …
Holmium (III) molecular nanomagnets for optical thermometry exploring the luminescence re-absorption effect
Coordination complexes of lanthanide (3+) ions can combine Single-Molecule Magnetism
(SMM) with thermally modulated luminescence applicable in optical thermometry. We report …
(SMM) with thermally modulated luminescence applicable in optical thermometry. We report …
A dysprosium single molecule magnet outperforming current pseudocontact shift agents
A common criterion for designing performant single molecule magnets and pseudocontact
shift tags is a large magnetic anisotropy. In this article we present a dysprosium complex …
shift tags is a large magnetic anisotropy. In this article we present a dysprosium complex …
Covalency and magnetic anisotropy in lanthanide single molecule magnets: the DyDOTA archetype
Lanthanide ions when complexed by polyamino-polycarboxylate chelators form a class of
compounds of paramount importance in several research and technological areas …
compounds of paramount importance in several research and technological areas …