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Resonant soft X‐ray scattering in polymer science
Resonant soft X‐ray scattering (RSoXS) is an emerging, powerful technique to probe the
nano‐to‐mesoscale structure of polymers and other molecules. It joins together small‐angle …
nano‐to‐mesoscale structure of polymers and other molecules. It joins together small‐angle …
Rapid ordering of block copolymer thin films
Block-copolymers self-assemble into diverse morphologies, where nanoscale order can be
finely tuned via block architecture and processing conditions. However, the ultimate usage …
finely tuned via block architecture and processing conditions. However, the ultimate usage …
Designing high χ copolymer materials for nanotechnology applications: A systematic bulk vs. thin films approach
This review article discusses the origins of self-assembly behavior of linear and non-linear
block co-and terpolymers and their application towards the fabrication of high-resolution …
block co-and terpolymers and their application towards the fabrication of high-resolution …
Recent applications of synchrotron radiation and neutrons in the study of soft matter
The broad range of applications of synchrotron and neutron scattering in the investigation of
soft condensed matter is reviewed. Appropriate combinations of these techniques allow …
soft condensed matter is reviewed. Appropriate combinations of these techniques allow …
Restructuring in block copolymer thin films: In situ GISAXS investigations during solvent vapor annealing
Block copolymer (BCP) thin films have been proposed for a number of nanotechnology
applications, such as nanolithography and as nanotemplates, nanoporous membranes and …
applications, such as nanolithography and as nanotemplates, nanoporous membranes and …
Self-assembly of ABC bottlebrush triblock terpolymers with evidence for looped backbone conformations
Bottlebrush block copolymers offer rich opportunities for the design of complex hierarchical
materials. As consequences of the densely grafted molecular architecture, bottlebrush …
materials. As consequences of the densely grafted molecular architecture, bottlebrush …
Latent alignment in pathway-dependent ordering of block copolymer thin films
Block copolymers spontaneously form well-defined nanoscale morphologies during thermal
annealing. Yet, the structures one obtains can be influenced by nonequilibrium effects …
annealing. Yet, the structures one obtains can be influenced by nonequilibrium effects …
Determination of interfacial mixing in tapered block polymer thin films: experimental and theoretical investigations
Tapered block polymers are an emerging class of macromolecules with unique and diverse
self-assembly behavior and properties. Herein, we directly examine the manipulation of self …
self-assembly behavior and properties. Herein, we directly examine the manipulation of self …
Spectral analysis for resonant soft X-ray scattering enables measurement of interfacial width in 3D organic nanostructures
Interfaces are of critical importance to many materials and phenomena yet are difficult to
probe. This difficulty is compounded in three-dimensional nanostructures and with delicate …
probe. This difficulty is compounded in three-dimensional nanostructures and with delicate …
Characterizing the Interface Scaling of High χ Block Copolymers near the Order–Disorder Transition
Advancements in the directed self-assembly of block copolymers (BCPs) have prompted the
development of new materials with larger effective interaction parameters (χe). This enables …
development of new materials with larger effective interaction parameters (χe). This enables …