The direct catalytic oxidation of methane to methanol—a critical assessment
Despite the large number of disparate approaches for the direct selective partial oxidation of
methane, none of them has translated into an industrial process. The oxidation of methane …
methane, none of them has translated into an industrial process. The oxidation of methane …
Homogeneous functionalization of methane
One of the remaining “grand challenges” in chemistry is the development of a next
generation, less expensive, cleaner process that can allow the vast reserves of methane …
generation, less expensive, cleaner process that can allow the vast reserves of methane …
Activation of C− H bonds by metal complexes
AE Shilov, GB Shul'pin - Chemical Reviews, 1997 - ACS Publications
Hydrocarbons, especially saturated hydrocarbons (alkanes), are the main constituents of oil
and natural gas, the feedstocks for chemical industry. Therefore, it is obvious that …
and natural gas, the feedstocks for chemical industry. Therefore, it is obvious that …
Homogeneous oxidation of alkanes by electrophilic late transition metals
SS Stahl, JA Labinger… - Angewandte Chemie …, 1998 - Wiley Online Library
The selective oxidation of alkanes is a topic of considerable interest to both industrial and
academic chemists. While the initial discovery occurred more than 25 years ago, new …
academic chemists. While the initial discovery occurred more than 25 years ago, new …
Selective alkane transformations via radicals and radical cations: Insights into the activation step from experiment and theory
As the main constituent of natural gas, alkanes are arguably Nature's most plentiful organic
base chemicals that are easily accessible. Chemists have long coveted the use of alkanes …
base chemicals that are easily accessible. Chemists have long coveted the use of alkanes …
Low-temperature, palladium (II)-catalyzed, solution-phase oxidation of methane to methanol derivative
LC Kao, AC Hutson, A Sen - Journal of the American Chemical …, 1991 - ACS Publications
Therefore, in order to remove all ambiguity concerning the source of the methyl group in
CF3C02Me, Pd (02CC2H5) 2 was used as the source for the Pd (II) ion. A further advantage …
CF3C02Me, Pd (02CC2H5) 2 was used as the source for the Pd (II) ion. A further advantage …
Highlights in the renaissance of amidometal chemistry
R Kempe - Angewandte Chemie International Edition, 2000 - Wiley Online Library
Turning a disadvantage to an advantage: The rather disappointing reactivity of the metal–
nitrogen bond in comparison to the metal–carbon bond resulted in the neglect of …
nitrogen bond in comparison to the metal–carbon bond resulted in the neglect of …
Selectivities in Hydrocarbon Activation: Kinetic and Thermodynamic Investigations of Reversible 1,2-RH-Elimination from (silox)2(tBu3SiNH)TiR (silox = tBu3SiO)
JL Bennett, PT Wolczanski - Journal of the American Chemical …, 1997 - ACS Publications
Addition of 2.0 equiv of Na (silox) to TiCl4 (THF) 2 afforded (silox) 2TiCl2 (1), which yielded
(silox) 2 (tBu3SiNH) TiCl (2-Cl) upon treatment with tBu3SiNLi. Grignard or alkyllithium …
(silox) 2 (tBu3SiNH) TiCl (2-Cl) upon treatment with tBu3SiNLi. Grignard or alkyllithium …
A review of the direct oxidation of methane to methanol
This article briefly reviewed the advances in the process of the direct oxidation of methane to
methanol (DMTM) with both heterogeneous and homogeneous oxidation. Attention was …
methanol (DMTM) with both heterogeneous and homogeneous oxidation. Attention was …
Mechanistic studies of Fujiwara hydroarylation. C− H activation versus electrophilic aromatic substitution
JA Tunge, LN Foresee - Organometallics, 2005 - ACS Publications
The addition of the C− H bonds of arenes across alkynes is catalyzed by Pd (OAc) 2 in
CF3CO2H (Fujiwara hydroarylation). Previously it has been suggested that this …
CF3CO2H (Fujiwara hydroarylation). Previously it has been suggested that this …