Spontaneous deracemizations

T Buhse, JM Cruz, ME Noble-Teran… - Chemical …, 2021 - ACS Publications
Spontaneous deracemizations is a challenging, multidisciplinary subject in current chirality
research. In the absence of any chiral inductors, an achiral substance or a racemic …

Strategies for chiral separation: from racemate to enantiomer

J Sui, N Wang, J Wang, X Huang, T Wang, L Zhou… - Chemical …, 2023 - pubs.rsc.org
Chiral separation has already become a crucial topic for effectively utilizing superfluous
racemates synthesized by chemical means and satisfying the growing requirements for …

Sonocrystallization: Monitoring and controlling crystallization using ultrasound

R Prasad, SV Dalvi - Chemical Engineering Science, 2020 - Elsevier
Crystallization is an extensively used unit operation for production of solid forms of inorganic
and organic compounds, pharmaceuticals, cosmetics, and polymers etc. However, the …

Overview of secondary nucleation: From fundamentals to application

S Xu, Z Hou, X Chuai, Y Wang - Industrial & Engineering …, 2020 - ACS Publications
Secondary nucleation can bring the crystallization process into a more easily controlled
state, and it is playing an important role in controlling crystal size distribution, polymorphism …

Ultrasound mechanisms and their effect on solid synthesis and processing: a review

C Devos, A Bampouli, E Brozzi, GD Stefanidis… - Chemical Society …, 2024 - pubs.rsc.org
Ultrasound proves to be an effective technique for intensifying a wide range of processes
involving solids and, as such, is often used to improve control over both solids formation and …

Particle breakage using wet mill, ultrasonic, and hydrodynamic cavitation

V Tiwari, G Walker, VV Ranade - Crystal Growth & Design, 2023 - ACS Publications
In-line fluidic devices and mills are often used for controlling crystal size distribution during
crystallization. In this work, we investigated the breakage of organic crystals in three particle …

Sonocrystallisation: Observations, theories and guidelines

J Jordens, B Gielen, C **ouras, MN Hussain… - … and Processing-Process …, 2019 - Elsevier
Crystallization is an important and widely used separation technique in the chemical and
pharmaceutical industry. Control of the final particle properties is of great importance for …

Designing single chirality via crystallization method: spontaneous chiral symmetry breaking and deracemization

B Zhang, X Sun, P Du - Materials Today Chemistry, 2023 - Elsevier
Obtaining pure enantiomers is crucial since the two enantiomers of chiral compounds can
exhibit vastly different optical, biological, and pharmacological properties. Two mixed …

Crystal growth, dissolution, and agglomeration kinetics of sodium chlorate

AA Fytopoulos, ME Kavousanakis… - Industrial & …, 2021 - ACS Publications
The analysis, development, and implementation of novel complex industrial crystallization
processes requires kinetic knowledge of not only crystal growth and nucleation but also …

Amplification of enantiomeric excess by dynamic inversion of enantiomers in deracemization of Au38 clusters

Y Wang, B Nieto-Ortega, T Bürgi - Nature communications, 2020 - nature.com
Symmetry breaking and amplification processes have likely played a fundamental role in the
development of homochirality on earth. Such processes have not been much studied for …