Chromatographic separation: A versatile strategy to prepare discrete and well-defined polymer libraries

EA Murphy, C Zhang, CM Bates… - Accounts of Chemical …, 2024 - ACS Publications
Conspectus The preparation of discrete and well-defined polymers is an emerging strategy
for emulating the remarkable precision achieved by macromolecular synthesis in nature …

Properties and applications of precision oligomer materials; where organic and polymer chemistry join forces

B van Genabeek, BAG Lamers… - Journal of Polymer …, 2021 - Wiley Online Library
Precise oligomeric materials constitute a growing area of research with implications for
various applications as well as fundamental studies. Notably, this field of science which can …

Mechanoredox catalysis enables a sustainable and versatile reversible addition‐fragmentation chain transfer polymerization process

P Chakma, SM Zeitler, F Baum, J Yu… - Angewandte …, 2023 - Wiley Online Library
The sustainable synthesis of macromolecules with control over sequence and molar mass
remains a challenge in polymer chemistry. By coupling mechanochemistry and electron …

Efficient creation and morphological analysis of ABC triblock terpolymer libraries

EA Murphy, YQ Chen, K Albanese… - …, 2022 - ACS Publications
Multiblock copolymers with increasingly complex block sequences─ for example, triblock
terpolymers─ offer unique opportunities to create nanostructured materials, but this …

Macromolecular engineering: from precise macromolecular inks to 3D printed microstructures

SO Catt, M Hackner, JP Spatz, E Blasco - Small, 2023 - Wiley Online Library
Macromolecules with complex, defined structures exist in nature but rarely is this degree of
control afforded in synthetic macromolecules. Sequence‐defined approaches provide a …

Low-Pressure Preparative Size-Exclusion Chromatography: from Narrow Disperse Polymer to Monodisperse Oligomer Batches

A Kleine, J Kimmig, C Mankel, US Schubert… - …, 2024 - ACS Publications
Redox-active conjugated oligo (quinoxaline) s as potential visible light-transparent charge
transport building blocks were synthesized, purified, and characterized. The Suzuki–Miyaura …

Accelerated discovery and map** of block copolymer phase diagrams

EA Murphy, SJ Skala, D Kottage, PA Kohl, Y Li… - Physical Review …, 2024 - APS
Block copolymers are widely used in many applications due to their spontaneous self-
assembly into a variety of nanoscale morphologies. However, a grand challenge in …

A highly flexible and adhesive polymer electrolyte with fast ion conduction prepared via UV-induced in-situ polymerization for lithium metal batteries

J Ma, Y Wu, L Dong, M Yu, Z Zhu, L Zhang… - Journal of Energy …, 2024 - Elsevier
Cathode–electrolyte integration via in-situ polymerization is an effective strategy to reduce
interfacial resistance in solid-state/quasi-solid-state lithium batteries; however, ion …

Narrowing down chain length effects on the antibacterial action of guanylated oligomers

D Wyers, T Jirapanjawat, JF Quinn, MR Whittaker… - Polymer …, 2023 - pubs.rsc.org
Synthesis of monodisperse guanylated oligomers through reversible addition fragmentation
chain transfer (RAFT) polymerization of 2-Boc aminoethyl acrylate followed by flash …

Determination of the critical chain length for macromolecular crystallization using structurally flexible polyketones

Y Ide, Y Manabe, Y Inaba, Y Kinoshita, J Pirillo… - Chemical …, 2022 - pubs.rsc.org
Critical chain length that divides small molecule crystallization from macromolecular
crystallization is an important index in macro-organic chemistry to predict chain-length …