Modeling the selective oxidation of n-butane to maleic anhydride: From active site to industrial reactor
In this contribution to the Special Issue honoring 100 very successful years of Casale SA, we
review and critically discuss the current status of modeling the most demanding selective …
review and critically discuss the current status of modeling the most demanding selective …
The Mechanism and Pathway of Selective Partial Oxidation of n-Butane to Maleic Anhydride Studied on Titanium Phosphate Catalysts
The partial selective oxidation of n-butane to maleic anhydride with molecular oxygen is
commercially well-established and strongly associated with the vanadium phosphorus oxide …
commercially well-established and strongly associated with the vanadium phosphorus oxide …
A conjugated heat and mass transfer model to implement reaction in particle-resolved CFD simulations of catalytic fixed bed reactors
Modelling catalytic fixed bed reactors with a small tube-to-particle diameter ratio requires a
detailed description of the interactions between fluid flow, intra-particle transport, and the …
detailed description of the interactions between fluid flow, intra-particle transport, and the …
[HTML][HTML] Mono-, Bi-, and Tri-metallic DES are prepared from Nb, Zr, and Mo for n-butane selective oxidation via VPO catalyst
In recent work, deep eutectic solvents (DESs) as ionic liquid analogues have been
abundantly used in catalysis. Herein, vanadium phosphorus oxide (VPO) catalysts were …
abundantly used in catalysis. Herein, vanadium phosphorus oxide (VPO) catalysts were …
Copper-based deep eutectic solvents (Cu-DES) assisted the VPO catalyst as a structural and electronic promoter for n-butane selective oxidation
Currently, deep eutectic solvents (DESs), as an exclusive class of ionic liquid analogs, are
extensively employed in various fields. Herein, vanadium phosphorus oxide (VPO) catalysts …
extensively employed in various fields. Herein, vanadium phosphorus oxide (VPO) catalysts …
Assessment of Concentration and Temperature Distribution in a Berty Reactor for an Exothermic Reaction
The Berty reactor is a continuously operated stirred tank reactor that is used in catalytic
experiments to achieve gradientless conditions. Uniformity of the concentration profile has …
experiments to achieve gradientless conditions. Uniformity of the concentration profile has …
[HTML][HTML] Rare earth metal based DES assisted the VPO synthesis for n-butane selective oxidation toward maleic anhydride
Deep eutectic solvents (DESs) are now considered a new class of ionic liquid analogs that
have been generously used in various fields. Herein, vanadium phosphorus oxide (VPO) …
have been generously used in various fields. Herein, vanadium phosphorus oxide (VPO) …
Phosphorus Dosing during Catalytic n-Butane Oxidation in a μ-Reactor: A Proof of Concept
The selective oxidation of n-butane to maleic anhydride over vanadium–phosphorus oxide
catalysts is subject to a dynamic change in the catalyst activity. This phenomenon is called …
catalysts is subject to a dynamic change in the catalyst activity. This phenomenon is called …
Regulation of Maleic Anhydride Selectivity for n-Butane Oxidation by Sb2O3-Modified Vanadium Phosphorus Oxide Catalysts
J Zhao, J Zhang, F Yang, T Yu, Q Li… - Industrial & …, 2024 - ACS Publications
Maleic anhydride (MA) is a significant chemical raw material to produce industrial products.
Vanadium phosphorus oxide (VPO) catalyst is considered an excellent catalyst for the …
Vanadium phosphorus oxide (VPO) catalyst is considered an excellent catalyst for the …
Investigating the accuracy of continuum models for the simulation of industrial maleic anhydride reactors: A comparative single particle CFD study
The selective oxidation of n-butane to maleic anhydride is a strongly exothermic reaction.
Resulting local hot-spots and intraparticle temperatures high above the surrounding fluid …
Resulting local hot-spots and intraparticle temperatures high above the surrounding fluid …