[HTML][HTML] Rearrangements of organic peroxides and related processes

IA Yaremenko, VA Vil, DV Demchuk… - Beilstein journal of …, 2016 - beilstein-journals.org
This review is the first to collate and summarize main data on named and unnamed
rearrangement reactions of peroxides. It should be noted, that in the chemistry of peroxides …

Theoretical chemical kinetics in tropospheric chemistry: methodologies and applications

L Vereecken, DR Glowacki, MJ Pilling - Chemical reviews, 2015 - ACS Publications
Chemical kinetics is central in much of tropospheric chemistry and in modeling tropospheric
chemical processes. Chemical reaction rate coefficients and product yields have traditionally …

Atmospheric chemistry of Criegee intermediates: Unimolecular reactions and reactions with water

B Long, JL Bao, DG Truhlar - Journal of the American Chemical …, 2016 - ACS Publications
Criegee intermediates are produced in the ozonolysis of unsaturated hydrocarbons in the
troposphere, and understanding their fate is a prerequisite to modeling climate-controlling …

The physical chemistry of Criegee intermediates in the gas phase

DL Osborn, CA Taatjes - International Reviews in Physical …, 2015 - Taylor & Francis
Carbonyl oxides, also known as Criegee intermediates, are key intermediates in both gas
phase ozonolysis of unsaturated hydrocarbons in the troposphere and solution phase …

Four-carbon Criegee intermediate from isoprene ozonolysis: Methyl vinyl ketone oxide synthesis, infrared spectrum, and OH production

VP Barber, S Pandit, AM Green… - Journal of the …, 2018 - ACS Publications
The reaction of ozone with isoprene, one of the most abundant volatile organic compounds
in the atmosphere, produces three distinct carbonyl oxide species (RR′ COO) known as …

Criegee intermediates: production, detection and reactivity

R Chhantyal-Pun, MAH Khan, CA Taatjes… - … Reviews in Physical …, 2020 - Taylor & Francis
In the context of tropospheric chemistry, Criegee intermediates denote carbonyl oxides with
biradical/zwitterionic character (R1R2COO) that form during the ozonolysis of alkenes. First …

Criegee intermediates beyond ozonolysis: Synthetic and mechanistic insights

Z Hassan, M Stahlberger… - Angewandte Chemie …, 2021 - Wiley Online Library
After more than 70 years since their discovery, Criegee intermediates (CIs) are back at the
forefront of modern chemistry of short‐lived reactive intermediates. They play an important …

Unimolecular decay of Criegee intermediates to OH radical products: prompt and thermal decay processes

MI Lester, SJ Klippenstein - Accounts of Chemical Research, 2018 - ACS Publications
Conspectus Alkene ozonolysis is a primary oxidation pathway for anthropogenic and
biogenic alkenes emitted into the troposphere. It is also an important source of atmospheric …

Atmospheric kinetics: bimolecular reactions of carbonyl oxide by a triple-level strategy

B Long, Y Wang, Y **a, X He, JL Bao… - Journal of the American …, 2021 - ACS Publications
Criegee intermediates in the atmosphere serve as oxidizing agents to initiate aerosol
formation, which are particularly important for atmospheric modeling, and understanding …

Cholesterol provides nonsacrificial protection of membrane lipids from chemical damage at air–water interface

X Zhang, KM Barraza… - Proceedings of the …, 2018 - National Acad Sciences
The role of cholesterol in bilayer and monolayer lipid membranes has been of great interest.
On the biophysical front, cholesterol significantly increases the order of the lipid packing …