Click chemistry is one of the most powerful strategies for constructing polymeric soft
materials with precise control over architecture and functionality. In this review, we provide a …

The widespread use of molecular machines in biology has long suggested that great
rewards could come from bridging the gap between synthetic molecular systems and the …

A mechanical bond serves as a distinctive approach for harnessing the most beneficial
features of both covalent and supramolecular chemistries, offering stability and structural …

With the advent of supramolecular chemistry and later nanotechnology a great deal of
research has been focused on new types of molecular structures, which are not held …

This review highlights developments since 2008 in the field of polypseudorotaxanes and
polyrotaxanes. Progress in synthetic polyrotaxane chemistry has resulted in the preparation …

Architecture underlies the thermomechanical properties of polymers. Yet, few strategies are
available to tune a polymer's architecture after it is prepared without altering its chemical …

The synthesis and dynamic nature of macromolecular systems controlled by rotaxane
macromolecular switches are introduced to discuss the significance of rotaxane linking of …

DOI: 10.1002/adma. 201506199 to proceed via a Grotthuss-type mechanism (schematic
illustrated in Figure 1A).[21–24] Several researchers have proposed that hydroxide ions are …

Mechanophores (mechanoresponsive molecules) offer great promises for the development
of smart force-responsive materials. The activity of a mechanophore can be tuned by altering …

Mechanical bonds are known to efficiently absorb mechanical energy at low forces, but their
behavior at high forces is unknown. Here we investigate the impact of a mechanical bond on …