A lithium halide exchange reaction at low-temperature, via the treatment of 2, 6-di (isopropyl)
phenyllithium on 1, 1′-bis-(dichlorophosphino) ferrocene, resulted in the first isolated …

Triphospha [3] ferrocenophane Fe (C5H4-PTip) 2PCl (Tip= 2, 4, 6-tri (isopropyl) phenyl) has
been prepared and its suitability to generate the corresponding bisphosphanylphosphenium …

Abstract tert‐Butyl‐substituted diphospha [2] ferrocenophane has been used as a
stereochemically confined diphosphane to explore the addition of O, S, Se and Te. Although …

Stereospecific access to the unprecedented P–B–P bridged [3] ferrocenophane Fe
(C5H4PtBu) 2BMes is presented. In contrast to acyclic ferrocenylphosphanes, we find …

A transient phosphenium cation embedded into a [3] ferrocenophane scaffold was formed
via chloride abstraction. The cation has been trapped with phosphane, carbene, and …

Coordination of a stereochemically defined P3‐chain to a series of transition metal
carbonyls [M (CO) x] z−(M= Mn (x= 5, z= 1), Fe (x= 4, z= 2) or Co (x= 4, z= 1)) is explored …

Unusual diastereomeric C1, C2, C3-functionalized carba [3] ferrocenophanes with two
stereogenic centres have been obtained using a ring closing reaction, based upon …

Abstract A series of bis‐[3] ferrocenophanes of the general type Fe (C5H4E') 2E− E
(E'C5H4) 2Fe (E= P, SiH and E'= PtBu, NneoPentyl, NSi (CH3) 3) with an isolobal molecular …

Donor stabilization of Sn (II) and Pb (II) halides with 1, 1'‐ferrocenylene bridged
bisphosphanes has been explored for Fe (C5H4P (C6H5) 2) 2 (dppf), and Fe (C5H4PH …

Condensation of secondary 1, 1′-diaminoferrocenes with phosphorus trihalides (PCl3 or
PBr3) yielded either P-halo-1, 3-diaza-2-phospha [3] ferrocenophanes or 1, 1 …