Metal-coordinated azoaromatics: Strategies for sequential azo-reduction, isomerization and application potential
Reversible electron reservoir feature of redox non-innocent ligand is an important event from
the broader perspectives of metal–ligand cooperativity in catalysis as well as in introducing …
the broader perspectives of metal–ligand cooperativity in catalysis as well as in introducing …
Metal–ligand cooperative approaches in homogeneous catalysis using transition metal complex catalysts of redox noninnocent ligands
Catalysis offers a straightforward route to prepare various value-added molecules starting
from readily available raw materials. The catalytic reactions mostly involve multi-electron …
from readily available raw materials. The catalytic reactions mostly involve multi-electron …
N-Alkylation of Amines by C1–C10 Aliphatic Alcohols Using A Well-Defined Ru(II)-Catalyst. A Metal–Ligand Cooperative Approach
A Ru (II)-catalyzed efficient and selective N-alkylation of amines by C1–C10 aliphatic
alcohols is reported. The catalyst [Ru (L1a)(PPh3) Cl2](1a) bearing a tridentate redox-active …
alcohols is reported. The catalyst [Ru (L1a)(PPh3) Cl2](1a) bearing a tridentate redox-active …
Amine Functionalized Pincer-like Azo-aromatic Complexes of Cobalt and Their Catalytic Activities in the Synthesis of Quinoline via Acceptorless Dehydrogenation of …
Herein we disclose a series of phosphine-free cobalt (II)-based catalytic systems bearing a
redox non-innocent amine functionalized azo-aromatic pincer-like ligand for the synthesis of …
redox non-innocent amine functionalized azo-aromatic pincer-like ligand for the synthesis of …
Dehydrogenative synthesis of quinolines, 2-aminoquinolines, and quinazolines using singlet diradical Ni (II)-catalysts
Simple, straightforward, and atom economic methods for the synthesis of quinolines, 2-
aminoquinolines, and quinazolines via biomimetic dehydrogenative condensation/coupling …
aminoquinolines, and quinazolines via biomimetic dehydrogenative condensation/coupling …
Metal–Ligand Cooperative Approach To Achieve Dehydrogenative Functionalization of Alcohols to Quinolines and Quinazolin-4(3H)-ones under Mild Aerobic …
A simple metal–ligand cooperative approach for the dehydrogenative functionalization of
alcohols to various substituted quinolines and quinazolin-4 (3 H)-ones under relatively mild …
alcohols to various substituted quinolines and quinazolin-4 (3 H)-ones under relatively mild …
Alcohol Dehydrogenation-Triggered Selective C3-Alkylation of Indoles by Homogeneous Azo-aromatic Cobalt Catalysts
Herein, we report azo-benzimidazole containing cobalt complexes (1–3) for alcohol
dehydrogenation-triggered C3-alkylation of indoles. In complexes 1–3, ligands are redox …
dehydrogenation-triggered C3-alkylation of indoles. In complexes 1–3, ligands are redox …
Ruthenium-catalyzed dehydrogenative functionalization of alcohols to pyrroles: a comparison between metal–ligand cooperative and non-cooperative approaches
Herein, we report the synthesis and characterization of two ruthenium-based pincer-type
catalysts,[1] X (X= Cl, PF6) and 2, containing two different tridentate pincer ligands, 2 …
catalysts,[1] X (X= Cl, PF6) and 2, containing two different tridentate pincer ligands, 2 …
Ligand-centred redox activation of inert organoiridium anticancer catalysts
WY Zhang, S Banerjee, GM Hughes… - Chemical …, 2020 - pubs.rsc.org
Organometallic complexes with novel activation mechanisms are attractive anticancer drug
candidates. Here, we show that half-sandwich iodido cyclopentadienyl iridium (III) …
candidates. Here, we show that half-sandwich iodido cyclopentadienyl iridium (III) …
Oxygen Dependent Switchable Selectivity during Ruthenium Catalyzed Selective Synthesis of C3-Alkylated Indoles and Bis(indolyl)methanes
Herein, we report a ligand-centered redox-controlled oxygen-dependent switchable
selectivity during ruthenium-catalyzed selective synthesis of C3-alkylated indoles and bis …
selectivity during ruthenium-catalyzed selective synthesis of C3-alkylated indoles and bis …