A comparison of RAFT and ATRP methods for controlled radical polymerization

NP Truong, GR Jones, KGE Bradford… - Nature Reviews …, 2021 - nature.com
Reversible addition–fragmentation chain-transfer (RAFT) polymerization and atom transfer
radical polymerization (ATRP) are the two most common controlled radical polymerization …

Atom transfer radical polymerization: a mechanistic perspective

F Lorandi, M Fantin… - Journal of the American …, 2022 - ACS Publications
Since its inception, atom transfer radical polymerization (ATRP) has seen continuous
evolution in terms of the design of the catalyst and reaction conditions; today, it is one of the …

Macromolecular engineering by atom transfer radical polymerization

K Matyjaszewski, NV Tsarevsky - Journal of the American …, 2014 - ACS Publications
This Perspective presents recent advances in macromolecular engineering enabled by
ATRP. They include the fundamental mechanistic and synthetic features of ATRP with …

Advanced materials by atom transfer radical polymerization

K Matyjaszewski - Advanced Materials, 2018 - Wiley Online Library
Atom transfer radical polymerization (ATRP) has been successfully employed for the
preparation of various advanced materials with controlled architecture. New catalysts with …

Toward green atom transfer radical polymerization: current status and future challenges

S Dworakowska, F Lorandi, A Gorczyński… - Advanced …, 2022 - Wiley Online Library
Reversible‐deactivation radical polymerizations (RDRPs) have revolutionized synthetic
polymer chemistry. Nowadays, RDRPs facilitate design and preparation of materials with …

Atom transfer radical polymerization: billion times more active catalysts and new initiation systems

TG Ribelli, F Lorandi, M Fantin… - Macromolecular rapid …, 2019 - Wiley Online Library
Approaching 25 years since its invention, atom transfer radical polymerization (ATRP) is
established as a powerful technique to prepare precisely defined polymeric materials. This …

Cu (0)-mediated living radical polymerization: a versatile tool for materials synthesis

A Anastasaki, V Nikolaou, G Nurumbetov… - Chemical …, 2016 - ACS Publications
During the past decade we have witnessed the rapid development and understanding of
living radical polymerization (LRP)(or reversible deactivation radical polymerizations …

Kinetics of atom transfer radical polymerization

P Krys, K Matyjaszewski - European Polymer Journal, 2017 - Elsevier
This review encompasses the fundamentals of kinetics of atom transfer radical
polymerization (ATRP). ATRP is a versatile reversible-deactivation radical polymerization …

Ultrasound and sonochemistry for radical polymerization: sound synthesis

TG McKenzie, F Karimi, M Ashokkumar… - … –A European Journal, 2019 - Wiley Online Library
The use of ultrasound as an external stimulus for promoting polymerization reactions has
received increasing attention in recent years. In this Review article, the fundamental …

How are radicals (re) generated in photochemical ATRP?

TG Ribelli, D Konkolewicz, S Bernhard… - Journal of the …, 2014 - ACS Publications
The polymerization mechanism of photochemically mediated Cu-based atom-transfer
radical polymerization (ATRP) was investigated using both experimental and kinetic …