The formation of isocyanurate via cyclotrimerization of isocyanates is widely reported to
provide a variety of polyurethane materials with improved chemical and physical properties …

The conjugated bis-guanidinate (CBG) supported zinc hydride,[{LZnH} 2; L={(ArHN)(ArN)-
C═ N–C═(NAr)(NHAr); Ar= 2, 6-Et2-C6H3}](1)(pre)-catalyzed addition of E–H (E= B, C, N …

Due to the upswing in interest in the development of efficient hydroelementation reactions to
construct C–heteroatom bonds either stoichiometrically or catalytically, the activation of …

A family of tin (II) guanidinate complexes of the general form [{RNC (NMe2) NR} 2Sn](R= iPr
(6), Cy (7), Tol (9) and Dipp (10)) and [{tBuNC (NMe2) NtBu} Sn {NMe2}](8) have been …

Cyclotrimerisation of isocyanates catalysed by low-coordinate Mn( ii ) and Fe( ii ) m -terphenyl
complexes - Chemical Communications (RSC Publishing) DOI:10.1039/C6CC07243G Royal …

A metal-free synthesis of symmetrical and unsymmetrical bulky N, N′-diaryl carbodiimides
from the dehydrosulfurisation of their corresponding N, N′-diarylthiourea with 4 …

We report the synthesis of aromatic germanimines [(HMDS) 2Ge═ NAr](Ar= Ph, Mes, Dipp;
Mes= 2, 4, 6-Me3C6H2, Dipp= 2, 6-i Pr2C6H3) and an investigation into their associated …

Novel homoleptic and heteroleptic (guanidinate) tin (II) complexes were successfully
synthesized and structurally characterized. The first heteroleptic (guanidinato) tin (II) …

Bulky guanidinate stabilized homoleptic complexes of [LM (thf) n L][L={ArNC (N i Pr 2)
NAr}(Ar= 2, 6-Me 2–C 6 H 3)]; M= Mg, Ca, and Zn; n= 0–1) have been synthesized with three …

The acetate-initiated aliphatic isocyanate trimerization to isocyanurate was investigated by
state-of-the-art analytical and computational methods. Although the common …