N-Heterocyclic carbenes (NHC) are nowadays ubiquitous and indispensable in many
research fields, and it is not possible to imagine modern transition metal and main group …

Hydroamination, an atom-economic one-step reaction that refers to the addition of an NH
unit into CC/CX multiple bonds, provides an ideally efficient methodology to construct C–N …

The design of molecular magnets has progressed greatly by taking advantage of the ability
to impart successive perturbations and control vibronic transitions in 4f n systems through …

Imidazolin-2-imines represent a particularly basic and nucleophilic subclass of guanidines,
and a large variety of these N-donor ligands have become available, inter alia, by the …

The heavier group 2 complexes [M {N (SiMe3) 2} 2] 2 (1, M= Ca; 2, M= Sr) and [M {CH
(SiMe3) 2} 2 (THF) 2](3, M= Ca; 4, M= Sr) are shown to be effective precatalysts for the …

The review summarizes advances in the chemistry of bis (alkyl) rare-earth complexes. The
methods of synthesis, structures, reactivity and catalytic activity of bis (alkyl) species …

An array of rare-earth bis (aminobenzyl) complexes supported by imidazolin-2-iminato
ligands were synthesized and structurally characterized. These complexes showed high …

An extended class of stable mesoionic N‐heterocyclic imines (mNHIs), containing a highly
polarized exocyclic imine moiety, were synthesized. The calculated proton affinities (PA) and …

The number of well-defined molybdenum and tungsten alkylidyne complexes that are able
to catalyze alkyne metathesis reactions efficiently has been significantly expanded in recent …

Lanthanide-based single-molecule magnets (Ln-SMMs) have become the most
conspicuous SMMs exhibiting the highest effective barrier (Ueff) and blocking temperature …