Metal-mediated and metal-catalyzed reactions of isocyanides
1. INTRODUCTION A timely subtitle to this Review focused on conversions of isocyanides at
metal centers could have been “a platinum jubilee of the first metal-mediated reaction …
metal centers could have been “a platinum jubilee of the first metal-mediated reaction …
Reactivity of acyclic diaminocarbene ligands
MA Kinzhalov, KV Luzyanin - Coordination Chemistry Reviews, 2019 - Elsevier
Acyclic diaminocarbenes (ADCs) are powerful ligands with a broad application scope in
organometallic chemistry, catalysis, photophysics and crystal engineering. Although the …
organometallic chemistry, catalysis, photophysics and crystal engineering. Although the …
Difference in Energy between Two Distinct Types of Chalcogen Bonds Drives Regioisomerization of Binuclear (Diaminocarbene)PdII Complexes
The reaction of cis-[PdCl2 (CNXyl) 2](Xyl= 2, 6-Me2C6H3) with various 1, 3-thiazol-and 1, 3,
4-thiadiazol-2-amines in chloroform gives a mixture of two regioisomeric binuclear …
4-thiadiazol-2-amines in chloroform gives a mixture of two regioisomeric binuclear …
Deprotonated diaminocarbene platinum complexes for thermoresponsive luminescent silicone materials: Both catalysts and luminophores
MV Dobrynin, SO Kasatkina, SV Baykov… - Dalton …, 2021 - pubs.rsc.org
C, N-Chelate deprotonated diaminocarbene platinum (II) complexes were synthesized by
coupling coordinated isocyanides and azinyl-substituted ureas. The complexes act as …
coupling coordinated isocyanides and azinyl-substituted ureas. The complexes act as …
Highly luminescent cyclometalated iridium complexes generated by nucleophilic addition to coordinated isocyanides
In this work, we report a new class of blue-emitting cyclometalated iridium complexes
supported by acyclic diaminocarbene (ADC) ancillary ligands. These neutral, tris-chelated …
supported by acyclic diaminocarbene (ADC) ancillary ligands. These neutral, tris-chelated …
Introducing Cationic Selenium-Containing Triazapentadiene Ligand Framework: Synthesis, Coordination Chemistry, and Antifungal Activity
AA Sapronov, VN Khrustalev, OG Chusova… - Inorganic …, 2024 - ACS Publications
Positively charged ligands are scarce. Here, we report the synthesis of unprecedented
cationic selenium-containing triazapentadiene ligand framework. The reaction between 2 …
cationic selenium-containing triazapentadiene ligand framework. The reaction between 2 …
Cyclometalated platinum (II) complexes with acyclic diaminocarbene ligands for OLED application
SA Katkova, DO Kozina, KS Kisel, MA Sandzhieva… - Dalton …, 2023 - pubs.rsc.org
A novel series of cyclometalated platinum (II) complexes bearing acyclic diaminocarbene
(ADC) ancillary ligands were designed and prepared. Their photophysical properties were …
(ADC) ancillary ligands were designed and prepared. Their photophysical properties were …
Synthesis and contemporary applications of platinum group metals complexes with acyclic diaminocarbene ligands
MA Kinzhalov, KV Luzyanin - Russian Journal of Inorganic Chemistry, 2022 - Springer
Complexes of platinum group metals with acyclic diaminocarbene ligands have found
application as transition metal catalysts, photoluminescent materials, chemosensors, and …
application as transition metal catalysts, photoluminescent materials, chemosensors, and …
Ligation-enhanced π-hole··· π interactions involving isocyanides: Effect of π-hole··· π noncovalent bonding on conformational stabilization of acyclic diaminocarbene …
The reaction of cis-[PdCl2 (CNXyl) 2](Xyl= 2, 6-Me2C6H3) with the aminoazoles [1 H-
imidazol-2-amine (1), 4 H-1, 2, 4-triazol-3-amine (2), 1 H-tetrazol-5-amine (3), 1 H …
imidazol-2-amine (1), 4 H-1, 2, 4-triazol-3-amine (2), 1 H-tetrazol-5-amine (3), 1 H …
Experimental and computational tuning of metalla-N-heterocyclic carbenes at palladium (ii) and platinum (ii) centers
MV Kashina, KV Luzyanin, EA Katlenok… - Dalton …, 2022 - pubs.rsc.org
Palladium (II) and platinum (II) complexes featuring metalla-N-heterocyclic carbenes (7–12)
were synthesised via metal-mediated coupling between equimolar cis-[MCl2 (CNR) 2](R= 2 …
were synthesised via metal-mediated coupling between equimolar cis-[MCl2 (CNR) 2](R= 2 …